An aliphatic MOF with a molecular sieving effect for efficient C 2 H 2 /C 2 H 4 separation.

Autor:	Li X; College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China. zhengniu@suda.edu.cn., Cao C; College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China. zhengniu@suda.edu.cn., Fan Z; College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China. zhengniu@suda.edu.cn., Liu J; College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China. zhengniu@suda.edu.cn., Pham T; Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE 205A, Tampa, Florida 33620-5250, USA., Forrest KA; Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE 205A, Tampa, Florida 33620-5250, USA., Niu Z; College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China. zhengniu@suda.edu.cn.
Jazyk:	angličtina
Zdroj:	Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2023 Oct 31; Vol. 52 (42), pp. 15338-15342. Date of Electronic Publication: 2023 Oct 31.
DOI:	10.1039/d3dt01419c
Abstrakt:	A metal-organic framework, SDMOF-1, with rigid pores of about 3.4 Å, which is appropriate for accommodating C 2 H 2 molecules, exhibits high C 2 H 2 adsorption capacity and great separation capability of the C 2 H 2 /C 2 H 4 mixture. This work provides a new method to design aliphatic MOFs with a molecular sieving effect to realize efficient gas separation.
Databáze:	MEDLINE
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