Tribovoltaic Performance of TiO 2 Thin Films: Crystallinity, Contact Metal, and Thermoelectric Effects.

Autor: Šutka A; Institute of Materials and Surface Engineering, Faculty of Materials Science and Applied Chemistry, Riga Technical University, Riga LV-1048, Latvia., Ma Lnieks K; Institute of Materials and Surface Engineering, Faculty of Materials Science and Applied Chemistry, Riga Technical University, Riga LV-1048, Latvia., Zubkins MR; Institute of Solid State Physics, University of Latvia, Kengaraga Street 8, Riga LV-1063, Latvia., Plu Dons AR; Institute of Materials and Surface Engineering, Faculty of Materials Science and Applied Chemistry, Riga Technical University, Riga LV-1048, Latvia., Šarakovskis A; Institute of Solid State Physics, University of Latvia, Kengaraga Street 8, Riga LV-1063, Latvia., Verners O; Institute of Materials and Surface Engineering, Faculty of Materials Science and Applied Chemistry, Riga Technical University, Riga LV-1048, Latvia., Egli Tis R; Institute of Materials and Surface Engineering, Faculty of Materials Science and Applied Chemistry, Riga Technical University, Riga LV-1048, Latvia., Sherrell PC; School of Chemical and Biomedical Engineering, Faculty of Engineering and Information Technology, The University of Melbourne, Parkville 3010, Australia.; School of Science, STEM College, RMIT University, Melbourne 3000, Australia.
Jazyk: angličtina
Zdroj: ACS applied materials & interfaces [ACS Appl Mater Interfaces] 2023 Jul 12; Vol. 15 (27), pp. 33140-33147. Date of Electronic Publication: 2023 Jun 28.
DOI: 10.1021/acsami.3c05830
Abstrakt: Tribovoltaic devices are attracting increasing attention as motion-based energy harvesters due to the high local current densities that can be generated. However, while these tribovoltaic devices are being developed, debate remains surrounding their fundamental mechanism. Here, we fabricate thin films from one of the world's most common oxides, TiO 2 , and compare the tribovoltaic performance under contact with metals of varying work functions, contact areas, and applied pressure. The resultant current density shows little correlation with the work function of the contact metal and a strong correlation with the contact area. Considering other effects at the metal-semiconductor interface, the thermoelectric coefficients of different metals were calculated, which showed a clear correlation with the tribovoltaic current density. On the microscale, molybdenum showed the highest current density of 192 mA cm -2 . This work shows the need to consider a variety of mechanisms to understand the tribovoltaic effect and design future exemplar tribovoltaic devices.
Databáze: MEDLINE