Assessing the Productivity of the Direct Conversion of Methane-to-Methanol over Copper-Exchanged Zeolite Omega (MAZ) via Oxygen Looping.

Autor: Wieser J; Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog Weg 1, 8093, Zürich, Switzerland., Knorpp AJ; Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog Weg 1, 8093, Zürich, Switzerland., Stoian DC; Swiss Norwegian beamlines (SNBL), European Synchrotron Radiation Facility, Avenue des Martyrs 71, 38043, Grenoble, France., Rzepka P; Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog Weg 1, 8093, Zürich, Switzerland.; Laboratory for catalysis and sustainable chemistry, Paul Scherrer Institute (PSI), Forschungsstrasse 111, 5232, Villigen, Switzerland., Newton MA; Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog Weg 1, 8093, Zürich, Switzerland., van Bokhoven JA; Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog Weg 1, 8093, Zürich, Switzerland.; Laboratory for catalysis and sustainable chemistry, Paul Scherrer Institute (PSI), Forschungsstrasse 111, 5232, Villigen, Switzerland.
Jazyk: angličtina
Zdroj: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2023 Oct 02; Vol. 62 (40), pp. e202305140. Date of Electronic Publication: 2023 Aug 08.
DOI: 10.1002/anie.202305140
Abstrakt: The methane-to-methanol (MtM) conversion via the oxygen looping approach using copper-exchanged zeolites has been extensively studied over the last decade. While a lot of research has focussed on maximizing yield and selectivity, little has been directed toward productivity-a metric far more meaningful for evaluating industrial potential. Using copper-exchanged zeolite omega (Cu-omega), a material highly active and selective for the MtM conversion using the isothermal oxygen looping approach, we show that this material exhibits unprecedented potential for industrial valorization. In doing so, we also present a novel methodology combining operando XAS and mass spectrometry for the screening of materials for the MtM conversion in oxygen looping mode.
(© 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)
Databáze: MEDLINE
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