Single molecule aggregation-induced dual and white-light emissive etherified aroyl- S , N -ketene acetals via one-pot synthesis.

Autor: Biesen L; Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf Universitätsstraße 1 D-40225 Düsseldorf Germany ThomasJJ.Mueller@hhu.de., Müller TJJ; Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf Universitätsstraße 1 D-40225 Düsseldorf Germany ThomasJJ.Mueller@hhu.de.
Jazyk: angličtina
Zdroj: RSC advances [RSC Adv] 2023 Jun 05; Vol. 13 (25), pp. 16867-16871. Date of Electronic Publication: 2023 Jun 05 (Print Publication: 2023).
DOI: 10.1039/d3ra02935b
Abstrakt: Etherified aroyl- S , N -ketene acetals are readily synthesized by a novel one-pot addition-elimination-Williamson-etherification sequence. Although the underlying chromophore remains constant, derivatives show pronounced color-tuning of solid-state emission and AIE characteristics, whereas a hydroxy-methyl derivative represents an easily accessible mono molecular aggregation-induced white-light emitter.
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE