Photocatalytic Charge-Transfer Complex Enables Hydroarylation of Alkenes for Heterocycle Synthesis.

Autor:	Ren YZ; Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi, Xinjiang 832000, People's Republic of China., Fang CZ; School of Chemical Sciences, University of Chinese Academy of Sciences Beijing 100049, People's Republic of China., Zhang BB; School of Chemical Sciences, University of Chinese Academy of Sciences Beijing 100049, People's Republic of China., He L; Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi, Xinjiang 832000, People's Republic of China., Tu YL; School of Chemical Sciences, University of Chinese Academy of Sciences Beijing 100049, People's Republic of China., Chen XY; School of Chemical Sciences, University of Chinese Academy of Sciences Beijing 100049, People's Republic of China.; Binzhou Institute of Technology, Weiqiao-UCAS Science and Technology Park, Binzhou, Shandong 256606, People's Republic of China.
Jazyk:	angličtina
Zdroj:	Organic letters [Org Lett] 2023 May 19; Vol. 25 (19), pp. 3585-3589. Date of Electronic Publication: 2023 May 08.
DOI:	10.1021/acs.orglett.3c01329
Abstrakt:	Here, we report a photocatalytic charge-transfer complex (CTC) strategy for one electron reduction of alkenes using thiolate as a catalytic electron donor. This catalytic CTC system could engage hydroarylation of both activated and unactivated alkenes for the synthesis of various heterocycles. The reactions do not require any photocatalysts or acids and are easy to perform. Mechanistic studies revealed the formation of a CTC between catalytic thiolate and alkene.
Databáze:	MEDLINE
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