| Autor: |
Ostermann M; CEST GmbH, Centre for Electrochemical Surface Technology, A-2700 Wiener Neustadt, Austria.; Institute of Physical Chemistry, University of Vienna, A-1090 Vienna, Austria., Bilotto P; CEST GmbH, Centre for Electrochemical Surface Technology, A-2700 Wiener Neustadt, Austria., Kadlec M; VZLU - Czech Aerospace Research Centre, CZ-199 05 Praha, Czech Republic., Schodl J; CEST GmbH, Centre for Electrochemical Surface Technology, A-2700 Wiener Neustadt, Austria., Duchoslav J; CEST GmbH, Centre for Electrochemical Surface Technology, A-2700 Wiener Neustadt, Austria.; Center for Surface and Nanoanalytics (ZONA), Johannes Kepler University Linz, A-4040 Linz, Austria., Stöger-Pollach M; University Service Centre for Transmission Electron Microscopy (USTEM), TU Wien, A-1040 Vienna, Austria.; Institute for Solid State Physics, TU Wien, A-1040 Vienna, Austria., Lieberzeit P; Institute of Physical Chemistry, University of Vienna, A-1090 Vienna, Austria., Valtiner M; CEST GmbH, Centre for Electrochemical Surface Technology, A-2700 Wiener Neustadt, Austria.; Applied Interface Physics, TU Wien, A-1040, Vienna, Austria. |
| Abstrakt: |
The aeronautical industry demands facile lightweight and low-cost solutions to address climate crisis challenges. Graphene can be a valid candidate to tackle these functionalities, although its upscalability remains difficult to achieve. Consequently, graphene-related materials (GRM) are gathering massive attention as top-down graphite exfoliation processes at the industrial scale are feasible and often employed. In this work, environmentally friendly produced partially oxidized graphene nanosheets (POGNs) reduced by green solvents such as l-Ascorbic Acid to rGNs are proposed to deliver functional coatings based on a glass fiber composite or coated Al2024 T3 for strategic R&D questions in the aeronautical industry, i.e. , low energy production, de-icing, and water uptake. In detail, energy efficiency in rGNs production is assessed via response-surface modeling of the powder conductivity, hence proposing an optimized reduction window. De-Icing functionality is verified by measuring the stable electrothermal property of an rGNs based composite over 24 h, and water uptake is elucidated by evaluating electrochemical and corrosion properties. Moreover, a mathematical model is proposed to depict the relation between the layers' sheet resistance and applied rGNs mass per area, which extends the system to other graphene-related materials, conductive two-dimensional materials, and various substrates. To conclude, the proposed system based on rGNs and epoxy paves the way for future multifunctional coatings, able to enhance the resistance of surfaces, such as airplane wings, in a flight harsh environment. |
