A review of the adsorption method for norfloxacin reduction from aqueous media.
Autor: | Ohale PE; Department of Chemical Engineering, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Nigeria., Igwegbe CA; Department of Chemical Engineering, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Nigeria.; Department of Applied Bioeconomy, Wroclaw University of Environmental and Life Sciences, Poland., Iwuozor KO; Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Nigeria.; Nigeria Sugar Institute, Ilorin, Nigeria., Emenike EC; Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Nigeria., Obi CC; Department of Chemical Engineering, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Nigeria.; Department of Polymer Engineering, Nnamdi Azikiwe University, P.M.B. 5025, Awka 420218, Nigeria., Białowiec A; Department of Applied Bioeconomy, Wroclaw University of Environmental and Life Sciences, Poland. |
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Jazyk: | angličtina |
Zdroj: | MethodsX [MethodsX] 2023 Apr 11; Vol. 10, pp. 102180. Date of Electronic Publication: 2023 Apr 11 (Print Publication: 2023). |
DOI: | 10.1016/j.mex.2023.102180 |
Abstrakt: | Norfloxacin (NRFX) is one of a class of antibiotics known as broad-spectrum fluoroquinolone antibiotic that is frequently used to treat infectious disorders in both animals and humans. NRFX is considered an emergent pharmaceutical contaminate. This review's objective is to evaluate empirical data on NRFX's removal from aqueous medium. The environmental danger of NRFX in the aquatic environment was validated by an initial ecotoxicological study. Graphene oxide/Metal Organic Framework (MOF) based composite, followed by Magnesium oxide/Chitosan/Graphene oxide composite gave the highest NRFX adsorption capacities (Qmax) of 1114.8 and 1000 mg/g, respectively. The main adsorption mechanisms for NRFX uptake include electrostatic interactions, H-bonds, π-π interactions, electron donor-acceptor interactions, hydrophobic interactions, and pore diffusion. The adsorptive uptake of NRFX were most suitably described by Langmuir isotherm and pseudo-second order implying adsorbate-to-adsorbent electron transfer on a monolayer surface. The thermodynamics of NRFX uptake is heavily dependent on the makeup of the adsorbent, and the selection of the eluent for desorption from the solid phase is equally important. There were detected knowledge gaps in column studies and adsorbent disposal method. There's great interest in scale-up and industrial applications of research results that will aid in management of water resources for sustainability. Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. (© 2023 The Authors.) |
Databáze: | MEDLINE |
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