Analytical assessment of modulated electric flux triggered degradation of chlorfenapyr and deltamethrin pesticides in guava fruits.

Autor: Ruman UE; Department of Chemistry, University of Gujrat, Gujrat, 57200, Pakistan. Electronic address: ummeruman120@gmail.com., Zubair M; Department of Chemistry, University of Gujrat, Gujrat, 57200, Pakistan. Electronic address: Muhammad.zubair@uog.edu.pk., Zeeshan MH; Chemical Engineering Department, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Perak, Malaysia.
Jazyk: angličtina
Zdroj: Analytical biochemistry [Anal Biochem] 2023 Jun 01; Vol. 670, pp. 115148. Date of Electronic Publication: 2023 Apr 04.
DOI: 10.1016/j.ab.2023.115148
Abstrakt: The purpose of this study was to explore the new effective method and investigate the dissipation of chlorfenapyr and deltamethrin (DM) pesticides used in the treatment of guava fruit from tropical and sub-tropical areas of Pakistan. Five different solutions of varying concentrations of pesticides were prepared. This study involved the in-vitro and in-vivo analysis of modulated electric flux-triggered degradation as an efficient method for the safer degradation of selected pesticides. The Taser gun was used as a tool for providing different numbers of electrical shocks of million voltages to the pesticides present in guava fruit at different temperatures. The degraded pesticides were extracted and analyzed by High-performance liquid chromatography (HPLC). The HPLC chromatograms verified that significant dissipation of pesticides took place when these were exposed to 9 shocks at 37 °C, which proved the efficiency of this degradation method. More than 50% of the total spray of both pesticides was dissipated. Thus, modulated electrical flux-triggered degradation is one of the effective methods for pesticide degradation.
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Databáze: MEDLINE