Development and optimization of geopolymer adsorbent for water treatment: Application of mixture design approach.

Autor: Aouan B; Mohammed V University in Rabat, Centre des Sciences des Matériaux, Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques (LPCMIO), Ecole Normale Supérieure (E.N.S), Rabat, Morocco. Electronic address: badr_aouan@um5.ac.ma., Alehyen S; Mohammed V University in Rabat, Centre des Sciences des Matériaux, Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques (LPCMIO), Ecole Normale Supérieure (E.N.S), Rabat, Morocco., Fadil M; Mohammed V University in Rabat, Centre des Sciences des Matériaux, Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques (LPCMIO), Ecole Normale Supérieure (E.N.S), Rabat, Morocco., El Alouani M; Mohammed V University in Rabat, Centre des Sciences des Matériaux, Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques (LPCMIO), Ecole Normale Supérieure (E.N.S), Rabat, Morocco., Saufi H; Mohammed V University in Rabat, Centre des Sciences des Matériaux, Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques (LPCMIO), Ecole Normale Supérieure (E.N.S), Rabat, Morocco., El Herradi EH; Mohammed V University in Rabat, Centre des Sciences des Matériaux, Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques (LPCMIO), Ecole Normale Supérieure (E.N.S), Rabat, Morocco., El Makhoukhi F; Centre National pour La Recherche Scientifique et Technique (CNRST-UATRS), Rabat, Morocco., Taibi M; Mohammed V University in Rabat, Centre des Sciences des Matériaux, Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques (LPCMIO), Ecole Normale Supérieure (E.N.S), Rabat, Morocco.
Jazyk: angličtina
Zdroj: Journal of environmental management [J Environ Manage] 2023 Jul 15; Vol. 338, pp. 117853. Date of Electronic Publication: 2023 Apr 02.
DOI: 10.1016/j.jenvman.2023.117853
Abstrakt: The current paper refers to the study of a new approach to optimizing the adsorptive properties of geopolymers by varying the aluminosilicate precursors from kaolin (K), metakaolin (MK), and coal fly ash (CFA) as internal synthesis factors. The simplex-augmented-centroid mixture design was applied to identify the optimal formulation from the three aluminosilicate precursors to develop a geopolymer (GP) with a distinctive structure that positively affects its dye adsorption efficiency. The variously formulated GP samples were tested for the removal of both methylene blue (MB-dye) and crystal violet dye (CV-dye) from an aqueous solution. The mathematical-statistical analysis of the experimental readings suggested that the generated special cubic models were significant, and thus the chosen approach was adequate for determining the optimum blending proportion. The optimization tools indicated that the optimal mixture from the three aluminosilicate precursors for developing a GP with high adsorption efficiency was 58% MK, 42% K, and 0% CFA. The optimized geopolymer (GP O ) was synthesized and then analyzed using a variety of physicochemical techniques, which revealed the presence of an amorphous N-A-S-H gel-rich porous structure as an influencing property on the geopolymer's organic dye adsorption efficiency. The dependence of the adsorption mechanism of both MB-dye and CV-dye by GP O on the adsorbent dosage, contact time, initial dye concentration, temperature, and solution pH was evaluated. The isothermic and kinetic experimental readings for MB and CV-dyes adsorption by GP O were well fitted to the pseudo-second-order and Freundlich models, with an exothermic, favorable, and spontaneous adsorption reaction thermodynamically. The experimental studies in the lab scale on GP O produce comparable results. From these results, it has been concluded that the accuracy and feasibility of the mixture design simulation succeeded in optimizing and developing a geopolymeric sorbent material with great potential as an excellent economical agent for removing cationic dyes from aqueous media. This point represents an added value compared to traditional non-optimized geopolymer absorbents. Besides, this geopolymer material represents a significant application possibility for water treatment and remediation of hazardous dye pollutants.
Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
(Copyright © 2023 Elsevier Ltd. All rights reserved.)
Databáze: MEDLINE
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