Jumping in the Chiral Pool: Asymmetric Hydroaminations with Early Metals.

Autor: Notz S; TU Chemnitz, Research Center for Materials, Architectures and Integration of Nanomembranes (MAIN), Research Group Organometallic Chemistry, Rosenbergstraße 6, D-09126 Chemnitz, Germany., Scharf S; TU Chemnitz, Research Center for Materials, Architectures and Integration of Nanomembranes (MAIN), Research Group Organometallic Chemistry, Rosenbergstraße 6, D-09126 Chemnitz, Germany., Lang H; TU Chemnitz, Research Center for Materials, Architectures and Integration of Nanomembranes (MAIN), Research Group Organometallic Chemistry, Rosenbergstraße 6, D-09126 Chemnitz, Germany.
Jazyk: angličtina
Zdroj: Molecules (Basel, Switzerland) [Molecules] 2023 Mar 16; Vol. 28 (6). Date of Electronic Publication: 2023 Mar 16.
DOI: 10.3390/molecules28062702
Abstrakt: The application of early-metal-based catalysts featuring natural chiral pool motifs, such as amino acids, terpenes and alkaloids, in hydroamination reactions is discussed and compared to those beyond the chiral pool. In particular, alkaline (Li), alkaline earth (Mg, Ca), rare earth (Y, La, Nd, Sm, Lu), group IV (Ti, Zr, Hf) metal-, and tantalum-based catalytic systems are described, which in recent years improved considerably and have become more practical in their usability. Additional emphasis is directed towards their catalytic performance including yields and regio- as well as stereoselectivity in comparison with the group IV and V transition metals and more widely used rare earth metal-based catalysts.
Databáze: MEDLINE
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