Insights about levels and source appointment of petroleum hydrocarbons in Brazilian semi-arid coastal: baseline status assessment for ocean decade targets.

Autor: de Oliveira AHB; Environmental Studies Laboratory (LEA), Federal University of Ceara, Analytical Chemistry and Physical Chemistry Dpto Campus Pici, Av. Mister Hull, S/N - Pici - 60455-760, Fortaleza, CE, Brazil. andrehbo@ufc.br.; Tropical Marine Sciences Program/LABOMAR/UFC, Fortaleza, Brazil. andrehbo@ufc.br., Fernandes GM; Laboratory for Assessment of Organic Contaminants (LACOr), Institute of Marine Sciences, Federal University of Ceara (LABOMAR-UFC), Av. Abolição, 3207-Meireles, Fortaleza, CE, 60165-081, Brazil., Dos Santos FR; Laboratory for Assessment of Organic Contaminants (LACOr), Institute of Marine Sciences, Federal University of Ceara (LABOMAR-UFC), Av. Abolição, 3207-Meireles, Fortaleza, CE, 60165-081, Brazil., de Almeida NM; Marine and Applied Geology Laboratory, Federal University of Ceara, Geology Dpto Campus Pici, Av. Mister Hull, S/N - Pici, 60440-554, Fortaleza, Brazil., Nogueira TR; Laboratory of Traces Analysis (LAT), Department of Analytical Chemistry and Physical Chemistry, Federal University of Ceara, Rua Do Contorno, Humberto Monte S/N Campus Do Pici, Bloco 940, Fortaleza, 60451-970, Brazil., de Quadros Melo D; Federal Institute of Education, Science and Technology of Sertão Pernambucano, PE 647, Km 22, PISNC N - 4, Rural Zone Petrolina Campus, Petrolina, PE, 56302-970, Brazil., Martins LL; Tropical Marine Sciences Program/LABOMAR/UFC, Fortaleza, Brazil.; Laboratory for Assessment of Organic Contaminants (LACOr), Institute of Marine Sciences, Federal University of Ceara (LABOMAR-UFC), Av. Abolição, 3207-Meireles, Fortaleza, CE, 60165-081, Brazil.; Laboratory of Petroleum Engineering and Exploration (LENEP), North Fluminense State University (UENF), Macaé, Rio de Janeiro, 27925-535, Brazil., Cavalcante RM; Tropical Marine Sciences Program/LABOMAR/UFC, Fortaleza, Brazil.; Laboratory for Assessment of Organic Contaminants (LACOr), Institute of Marine Sciences, Federal University of Ceara (LABOMAR-UFC), Av. Abolição, 3207-Meireles, Fortaleza, CE, 60165-081, Brazil., do Nascimento RF; Laboratory of Traces Analysis (LAT), Department of Analytical Chemistry and Physical Chemistry, Federal University of Ceara, Rua Do Contorno, Humberto Monte S/N Campus Do Pici, Bloco 940, Fortaleza, 60451-970, Brazil., Reddy CM; Department of Marine Chemistry and Geochemistry, Woods Hole Oceanographic Institution, Woods Hole, MA, 02543, USA.
Jazyk: angličtina
Zdroj: Environmental science and pollution research international [Environ Sci Pollut Res Int] 2023 Apr; Vol. 30 (20), pp. 58002-58018. Date of Electronic Publication: 2023 Mar 28.
DOI: 10.1007/s11356-023-26600-6
Abstrakt: The Ocean decade (2021-2030) for sustainable development proclaimed in 2017 by the UN, seeks to promote and conserve the sustainable use of oceans, seas, and marine resources. For this, the distribution of n-alkanes, polycyclic aromatic hydrocarbons (PAHs), and biomarkers, in sediments from the Fortaleza coastal zone (Mucuripe harbor (MH) and Inner Continental shelf (ICS)) were used to assess the impacts of anthropogenic activities in the area. The concentrations of total n-alkanes (Σ16 n-alkanes) in MH and ICS sediments varied from 35.9 to 94.9 and 17.9 to 197.3 μg g -1 , respectively, while the isoprenoids phytane and pristane in MH and ICS sediments ranged from 0.1 to 1.69 ug g -1 and from 0.14 and 1.20 μg g -1 , respectively. Most of the sediment samples presented carbon preference index (CPI) values close to unity, indicating that the area is submitted to petroleum-related sources. The concentrations of Σ16 PAHs in MH and ICS sediments varied from 87.0 to 562.0 and 98 to 288.0 ng g -1 . This work presents the first investigation of the petroleum biomarkers hopanes and steranes in the Fortaleza coastal zone, in which ΣBiomarkers varied from 0.10 to 1.79 and 0.02 to 0.24 ug g -1 in MH and ICS sediments, respectively. The presence at stations of biomarkers also indicates petrogenic input. The diagnosis of the distribution of pollutants in the investigated zones of the Fortaleza coast suggests contamination from urban areas and oil spills and vessel traffic.
(© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)
Databáze: MEDLINE
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