| Autor: |
Takamuku T; Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi, Saga 840-8502, Japan. takamut@cc.saga-u.ac.jp., Nishiyama D; Functional Biomolecular Science, Graduate School of Advanced Health Sciences, Saga University, Honjo-machi, Saga 840-8502, Japan., Kawano M; Department of Chemistry and Applied Chemistry, Graduate School of Science and Engineering, Saga University, Honjo-machi, Saga 840-8502, Japan., Miannay FA; Laboratoire de Spectrochimie Infrarouge et Raman, UMR CNRS A8516, Université de Lille, Science et Technologies, 59655 Villeneuve d'Ascq, France., Idrissi A; Laboratoire de Spectrochimie Infrarouge et Raman, UMR CNRS A8516, Université de Lille, Science et Technologies, 59655 Villeneuve d'Ascq, France. |
| Jazyk: |
angličtina |
| Zdroj: |
Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2023 Apr 05; Vol. 25 (14), pp. 9868-9880. Date of Electronic Publication: 2023 Apr 05. |
| DOI: |
10.1039/d2cp05858h |
| Abstrakt: |
In order to determine the self-diffusion coefficients D of all the species in the solutions at 298.2 K, 1 H and 19 F NMR diffusion ordered spectroscopy (DOSY) has been conducted on coumarin 153 (C153) in binary mixed solvents of an imidazolium-based ionic liquid (IL), 1-dodecyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide (C 12 mimTFSA), with three molecular liquids (MLs) of chloroform (CL), benzene (BZ), and propylene carbonate (PC) as a function of ML mole fraction x ML . Below x ML ≈ 0.8, the D values of each species do not significantly depend on the MLs. However, above this mole fraction, the diffusion of C153 becomes smoother in the order of BZ ≈ CL > PC systems. The interactions among C153, C 12 mim + , TFSA - , and ML molecules have been investigated using infrared (IR) and 1 H and 13 C NMR spectroscopic techniques. The relations of the diffusion of the species with the interactions among them have been discussed on the molecular scale. In the IL solution, the C153 carbonyl oxygen atom is hydrogen-bonded with the imidazolium ring C 2 -H atom of C 12 mim + . C 12 mim + also forms an ion pair with TFSA - . Thus, C153, C 12 mim + , and TFSA - cooperatively move in the CL and BZ solutions at a lower ML content, x ML < ∼0.8. On the other hand, at a higher ML content, x ML > ∼0.8, the C153 molecule diffuses with CL and BZ molecules because of the hydrogen bonding between the C153 carbonyl O atom and the CL H atom and the π-π interaction between the C153 and BZ ring planes, respectively. For the PC system, the change in the relative self-diffusion coefficients of each species with increasing x ML differs from those for the CL and BZ systems because of both hydrogen bonding donor H and acceptor O atoms of PC for C153, the IL cation and anion, and PC themselves. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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