Transition Metal-Catalyzed C-H Functionalization Through Electrocatalysis.

Autor: Baroliya PK; Department of Chemistry, Indian Institute of Technology Bombay Powai, Mumbai, 400076, India.; Department of Chemistry, Mohanlal Sukhadia University, Udaipur, 313001, India., Dhaker M; Department of Chemistry, Mohanlal Sukhadia University, Udaipur, 313001, India., Panja S; Department of Chemistry, Indian Institute of Technology Bombay Powai, Mumbai, 400076, India., Al-Thabaiti SA; Department of Chemistry, Faculty of Sciences, King Abdulaziz University, Jeddah, 21589, Saudi Arabia., Albukhari SM; Department of Chemistry, Faculty of Sciences, King Abdulaziz University, Jeddah, 21589, Saudi Arabia., Alsulami QA; Department of Chemistry, Faculty of Sciences, King Abdulaziz University, Jeddah, 21589, Saudi Arabia., Dutta A; Department of Chemistry, Indian Institute of Technology Bombay Powai, Mumbai, 400076, India., Maiti D; Department of Chemistry, Indian Institute of Technology Bombay Powai, Mumbai, 400076, India.
Jazyk: angličtina
Zdroj: ChemSusChem [ChemSusChem] 2023 Jun 22; Vol. 16 (12), pp. e202202201. Date of Electronic Publication: 2023 Apr 24.
DOI: 10.1002/cssc.202202201
Abstrakt: Electrochemically promoted transition metal-catalyzed C-H functionalization has emerged as a promising area of research over the last few decades. However, development in this field is still at an early stage compared to traditional functionalization reactions using chemical-based oxidizing agents. Recent reports have shown increased attention on electrochemically promoted metal-catalyzed C-H functionalization. From the standpoint of sustainability, environmental friendliness, and cost effectiveness, electrochemically promoted oxidation of a metal catalyst offers a mild, efficient, and atom-economical alternative to traditional chemical oxidants. This Review discusses advances in the field of transition metal-electrocatalyzed C-H functionalization over the past decade and describes how the unique features of electricity enable metal-catalyzed C-H functionalization in an economic and sustainable way.
(© 2023 Wiley-VCH GmbH.)
Databáze: MEDLINE
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