Marigold Flower-Shaped Metal-Organic Framework Supported Manganese Vanadium Oxide Electrocatalyst for Efficient Oxygen Evolution Reactions in an Alkaline Medium.

Autor: Ji SM; Department of Nano Convergence Engineering, Jeonbuk National University, 561-756, Jeonju, Republic of Korea., Muthurasu A; Department of Nano Convergence Engineering, Jeonbuk National University, 561-756, Jeonju, Republic of Korea., Kim HY; Department of Nano Convergence Engineering, Jeonbuk National University, 561-756, Jeonju, Republic of Korea.; Department of Organic Materials and Fiber Engineering, Jeonbuk National University, 561-756, Jeonju, Republic of Korea.
Jazyk: angličtina
Zdroj: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2023 May 11; Vol. 29 (27), pp. e202300137. Date of Electronic Publication: 2023 Mar 23.
DOI: 10.1002/chem.202300137
Abstrakt: The electrochemical oxygen evolution reaction (OER) is a key process in many renewable energy systems. The development of low-cost, long-lasting alternatives to precious-metal catalysts, particularly functional electrocatalysts with high activity for OER processes, is crucial for reducing the operating expense and complexity of renewable energy generating systems. This work describes a concise method for generating marigold flower-like metal-organic frameworks (MOFs) aided manganese vanadium oxide via a hydrothermal procedure for increased OER activity. As synthesized MOF MnV oxide has a higher surface area due to the 3D flower-like structure, which is reinvented with enhanced electrocatalytic active sites. These distinctive structural features result in remarkable catalytic activity for MOF MnV oxide microflowers towards OER with a low overpotential of 310 mV at 50 mA cm -2 and a Tafel slope with only 51.4 mV dec -1 in alkaline conditions. This study provides a concise method for developing an optimized catalytic material with greater morphology and beneficial features for potential energy and environmental applications.
(© 2023 Wiley-VCH GmbH.)
Databáze: MEDLINE
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