| Autor: |
Lomov SV; Center for Petroleum Science and Engineering, Skolkovo Institute of Science and Technology, Bolshoy Boulevard 30 bld. 1, Moscow 121205, Russia., Akmanov IS; Center for Petroleum Science and Engineering, Skolkovo Institute of Science and Technology, Bolshoy Boulevard 30 bld. 1, Moscow 121205, Russia., Liu Q; State Key Laboratory of Mechanics and Control of Mechanical Structures, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China., Wu Q; State Key Laboratory of Mechanics and Control of Mechanical Structures, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China., Abaimov SG; Center for Petroleum Science and Engineering, Skolkovo Institute of Science and Technology, Bolshoy Boulevard 30 bld. 1, Moscow 121205, Russia. |
| Jazyk: |
angličtina |
| Zdroj: |
Polymers [Polymers (Basel)] 2023 Jan 29; Vol. 15 (3). Date of Electronic Publication: 2023 Jan 29. |
| DOI: |
10.3390/polym15030678 |
| Abstrakt: |
Temperature dependence of electrical conductivity/resistivity of CNT networks (dry or impregnated), which is characterised by a temperature coefficient of resistance (TCR), is experimentally observed to be negative, especially for the case of aligned CNT (A-CNT). The paper investigates the role of three phenomena defining the TCR, temperature dependence of the intrinsic conductivity of CNTs, of the tunnelling resistance of their contacts, and thermal expansion of the network, in the temperature range 300-400 K. A-CNT films, created by rolling down A-CNT forests of different length and described in Lee et al., Appl Phys Lett, 2015, 106: 053110, are investigated as an example. The modelling of the electrical conductivity is performed by the nodal analysis of resistance networks, coupled with the finite-element thermomechanical modelling of network thermal expansion. The calculated TCR for the film is about -0.002 1/K and is close to the experimentally observed values. Comparative analysis of the influence of the TCR defining phenomena is performed on the case of dry and impregnated films. The analysis shows that in both cases, for an A-CNT film at the studied temperature interval, the main factor affecting a network's TCR is the TCR of the CNTs themselves. The TCR of the tunnelling contacts plays the secondary role; influence of the film thermal expansion is marginal. The prevailing impact of the intrinsic conductivity TCR on the TCR of the film is explained by long inter-contact segments of CNTs in an A-CNT network, which define the homogenised film conductivity. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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