Effects of the diphenyl ether additive in halogen-free processed non-fullerene acceptor organic solar cells.

Autor:	Di Mario L; Zernike Institute for Advanced Materials, University of Groningen Nijenborgh 4 Groningen 9747 AG The Netherlands m.a.loi@rug.nl., Garcia Romero D; Zernike Institute for Advanced Materials, University of Groningen Nijenborgh 4 Groningen 9747 AG The Netherlands m.a.loi@rug.nl., Pieters MJ; Zernike Institute for Advanced Materials, University of Groningen Nijenborgh 4 Groningen 9747 AG The Netherlands m.a.loi@rug.nl., Eller F; Dynamics and Structure Formation - Herzig Group, Institute of Physics, University of Bayreuth Universitätsstraße 30 Bayreuth 95447 Germany., Zhu C; Lawrence Berkeley National Laboratory, Advanced Light Source Berkeley CA 94720 USA., Bongiovanni G; Dipartimento di Fisica, Università degli Studi di Cagliari Monserrato I-09042 Italy., Herzig EM; Dynamics and Structure Formation - Herzig Group, Institute of Physics, University of Bayreuth Universitätsstraße 30 Bayreuth 95447 Germany., Mura A; Dipartimento di Fisica, Università degli Studi di Cagliari Monserrato I-09042 Italy., Loi MA; Zernike Institute for Advanced Materials, University of Groningen Nijenborgh 4 Groningen 9747 AG The Netherlands m.a.loi@rug.nl.
Jazyk:	angličtina
Zdroj:	Journal of materials chemistry. A [J Mater Chem A Mater] 2023 Jan 16; Vol. 11 (5), pp. 2419-2430. Date of Electronic Publication: 2023 Jan 16 (Print Publication: 2023).
DOI:	10.1039/d2ta08603d
Abstrakt:	The development of an environmentally friendly fabrication process for non-fullerene acceptor organic solar cells is an essential condition for their commercialization. However, devices fabricated by processing the active layer with green solvents still struggle to reach, in terms of efficiency, the same performance as those fabricated with halogenated solvents. The reason behind this is the non-optimal nanostructure of the active layer obtained with green solvents. Additives in solution have been used to fine-tune the nanostructure and improve the performance of organic solar cells. Therefore, the identification of non-halogenated additives and the study of their effects on the device performance and stability are of primary importance. In this work, we propose the use of diphenyl ether (DPE) as additive, in combination with the non-halogenated solvent o -xylene, to fabricate organic solar cells with a completely halogen-free process. Thanks to the addition of DPE, a best efficiency of 11.7% have been obtained for the system TPD-3F:IT-4F, an increase over 15% with respect to the efficiency of devices fabricated without additive. Remarkably, the stability under illumination of the solar cells is also improved when DPE is used. The addition of DPE has effects on the molecular organization in the active layer, with an enhancement in the donor polymer ordering, showing a higher domain purity. The resulting structure improves the charge carrier collection, leading to a superior short-circuit current and fill factor. Furthermore, a reduction of the non-radiative recombination losses and an improved exciton diffusion, are the results of the superior molecular ordering. With a comprehensive insight of the effects of DPE when used in combination with a non-halogenated solvent, our study provides an approach to make the fabrication of organic solar cell environmentally friendlier and more suitable for large scale production. Competing Interests: The authors declare no conflict of interest. (This journal is © The Royal Society of Chemistry.)
Databáze:	MEDLINE
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