Diffusion Anisotropy of Gaseous Helium-3 in Ordered Aerogels at Low Temperatures.

Autor:	Kuzmin V; Institute of Physics, Kazan Federal University, 420008Kazan, Russia., Safiullin K; Institute of Physics, Kazan Federal University, 420008Kazan, Russia., Stanislavovas A; Institute of Physics, Kazan Federal University, 420008Kazan, Russia., Baibekov E; Institute of Physics, Kazan Federal University, 420008Kazan, Russia., Tagirov M; Institute of Physics, Kazan Federal University, 420008Kazan, Russia.; Tatarstan Academy of Sciences, 420111Kazan, Russia.
Jazyk:	angličtina
Zdroj:	The journal of physical chemistry. B [J Phys Chem B] 2023 Feb 16; Vol. 127 (6), pp. 1459-1470. Date of Electronic Publication: 2023 Feb 05.
DOI:	10.1021/acs.jpcb.2c08251
Abstrakt:	We report on the first observation of diffusion anisotropy of gaseous helium-3 entrapped in ordered aerogels at 4.2 K. The origins of 3 He diffusion anisotropy in aerogels of different porosity are discussed. The correlations between gas diffusion coefficient and basic parameters of aerogels, such as porosity, fiber diameter, and fiber's degree of alignment, are inspected using simple diffusion simulations within the framework of classical diffusion model in both oriented and chaotic aerogels under conditions of diffuse (Knudsen diffusion) and specular reflections of atoms from the walls. The failure of the two-phase and Knudsen diffusion models at low temperature in isotropic and anisotropic aerogels is observed. The effect of a wall attractive potential on the gas dynamics is suspected to play a crucial role in the gas diffusion and its anisotropy. The rough theoretical estimates of that effect at low temperatures in aerogel space confirm this assumption. The observed peculiar diffusion is universal and is expected to occur with other probe gases at higher temperatures.
Databáze:	MEDLINE
Externí odkaz:	Zobrazit plný text záznamu