Pu 5f Occupation in Plutonium Dioxide.

Autor: Tobin JG; University of Wisconsin-Oshkosh, Oshkosh, Wisconsin 54901, United States., Yu SW; Lawrence Livermore National Laboratory, Livermore, California 94550, United States.
Jazyk: angličtina
Zdroj: Inorganic chemistry [Inorg Chem] 2023 Feb 13; Vol. 62 (6), pp. 2592-2598. Date of Electronic Publication: 2023 Feb 02.
DOI: 10.1021/acs.inorgchem.2c03202
Abstrakt: An actinide N 4,5 branching ratio analysis of PuO 2 and UO 2 has been performed, including measurements with a scanning transmission electron microscope at the Advanced Light Source. It is shown that the 5f occupation of the Pu in plutonium dioxide is n = 5. This is contrary to recent results from another technique.
Databáze: MEDLINE