Structural insight into the magnesium borohydride - ethylenediamine solid-state Mg-ion electrolyte system.

Autor: Golub IE; Institute of Condensed Matter and Nanosciences (IMCN), Université catholique de Louvain (UCLouvain), 1348, Louvain-la-Neuve, Belgium. m.heere@tu-bs.de., Heere M; Institute for Applied Materials-Energy Storage Systems (IAM-ESS), Karlsruhe Institute of Technology (KIT), 76344 Eggenstein, Germany.; Technische Universität Braunschweig, Institute of Internal Combustion Engines, Hermann-Blenk-Straße 42, 38108 Braunschweig, Germany., Gounaris V; Institute of Condensed Matter and Nanosciences (IMCN), Université catholique de Louvain (UCLouvain), 1348, Louvain-la-Neuve, Belgium. m.heere@tu-bs.de., Li X; Institute of Condensed Matter and Nanosciences (IMCN), Université catholique de Louvain (UCLouvain), 1348, Louvain-la-Neuve, Belgium. m.heere@tu-bs.de., Steenhaut T; Institute of Condensed Matter and Nanosciences (IMCN), Université catholique de Louvain (UCLouvain), 1348, Louvain-la-Neuve, Belgium. m.heere@tu-bs.de., Wang J; Institute of Condensed Matter and Nanosciences (IMCN), Université catholique de Louvain (UCLouvain), 1348, Louvain-la-Neuve, Belgium. m.heere@tu-bs.de., Robeyns K; Institute of Condensed Matter and Nanosciences (IMCN), Université catholique de Louvain (UCLouvain), 1348, Louvain-la-Neuve, Belgium. m.heere@tu-bs.de., Li HW; Hefei General Machinery Research Institute (HGMRI), Hefei 230031, China., Dovgaliuk I; Swiss-Norwegian Beamlines, European Synchrotron Radiation Facility, 71 Rue des Martyrs, Grenoble, 38043, France.; Institut des Matériaux Poreux de Paris, Ecole Normale Supérieure, ESPCI Paris, CNRS, PSL Université, 75005 Paris, France., Ikeda K; Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), Tsukuba, Ibaraki 305-0801, Japan., Hautier G; Institute of Condensed Matter and Nanosciences (IMCN), Université catholique de Louvain (UCLouvain), 1348, Louvain-la-Neuve, Belgium. m.heere@tu-bs.de., Filinchuk Y; Institute of Condensed Matter and Nanosciences (IMCN), Université catholique de Louvain (UCLouvain), 1348, Louvain-la-Neuve, Belgium. m.heere@tu-bs.de.
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2023 Feb 21; Vol. 52 (8), pp. 2404-2411. Date of Electronic Publication: 2023 Feb 21.
DOI: 10.1039/d2dt03567g
Abstrakt: A highly complex crystal structure of stoichiometric Mg 5 ( en ) 6 (BH 4 ) 10 was solved from single crystal synchrotron X-ray diffraction and confirmed by neutron powder diffraction (NPD) on isotopically substituted Mg( en ) 1.2 ( 11 BD 4 ) 2 . We highlight the role of the amorphous Mg(BH 4 ) 2 in the reactivity of the Mg(BH 4 ) 2 - en system and characterized a previously overlooked phase, Mg( en ) 2 (BH 4 ) 2 .
Databáze: MEDLINE
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