The enhancement of dye filtration performance and antifouling properties in amino-functionalized bentonite/polyvinylidene fluoride mixed matrix membranes.

Autor: Pramono E; Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jalan Ganesha no. 10, Bandung, 40132, Indonesia.; Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami no. 36A, Surakarta, 57216, Indonesia., Umam K; Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jalan Ganesha no. 10, Bandung, 40132, Indonesia.; Textile Chemistry Division, Politeknik STTT Bandung, Jl. Jakarta no. 31, Bandung, 40272, Indonesia., Sagita F; Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jalan Ganesha no. 10, Bandung, 40132, Indonesia., Saputra OA; Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami no. 36A, Surakarta, 57216, Indonesia., Alfiansyah R; Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jalan Ganesha no. 10, Bandung, 40132, Indonesia., Setyawati Dewi RS; Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jalan Ganesha no. 10, Bandung, 40132, Indonesia., Kadja GTM; Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jalan Ganesha no. 10, Bandung, 40132, Indonesia.; Center for Catalysis and Reaction Engineering, Institut Teknologi Bandung, Jalan Ganesha no. 10, Bandung, 40132, Indonesia.; Research Center for Nanosciences and Nanotechnology, Institut Teknologi Bandung, Jalan Ganesha no. 10, Bandung, 40132, Indonesia., Ledyastuti M; Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jalan Ganesha no. 10, Bandung, 40132, Indonesia., Wahyuningrum D; Organic Chemistry Division, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jalan Ganesha no. 10, Bandung, 40132, Indonesia., Radiman CL; Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jalan Ganesha no. 10, Bandung, 40132, Indonesia.
Jazyk: angličtina
Zdroj: Heliyon [Heliyon] 2023 Jan 05; Vol. 9 (1), pp. e12823. Date of Electronic Publication: 2023 Jan 05 (Print Publication: 2023).
DOI: 10.1016/j.heliyon.2023.e12823
Abstrakt: Trade-off issue and membrane fouling remain two major issues in the utilization of membrane technology for the water treatment due to reduced membrane permeability and lifetime. In our study, we employed 3-aminopropyltriethoxysilane modified bentonite (BNTAPS) as an anti-fouling modifier to prepare polyvinylidene fluoride (PVDF)-based membranes via the phase inversion method. The effects of BNTAPS concentration on the physical, mechanical, morphological, and filtration performance of the hybrid membranes have been investigated. It was found that the addition of BNTAPS improved the hydrophilicity of the membrane revealed by the decreased water contact angle. Consequently, the pure water flux of PVDF membrane containing 0.5% BNTAPS (PVDF/BNTAPS0.5%) increased to 35.5 L m -2  h -1 . Moreover, the PVDF/BNTAPS membrane showed a smaller pore diameter and porosity compared to pristine PVDF. The membrane performance evaluation was carried out using cationic and anionic dyes, i.e., methylene blue (MB) and acid yellow (AY17), respectively. Our study revealed that the rejection of each dye was slightly increased for the PVDF/BNTAPS0.5%. However, the flux recovery rate of the PVDF/BNTAPS membrane significantly improved, which directly prolonged the membrane lifetime.
(© 2023 The Authors.)
Databáze: MEDLINE