The Photocatalytic Conversion of Carbon Dioxide to Fuels Using Titanium Dioxide Nanosheets/Graphene Oxide Heterostructure as Photocatalyst.

Autor: Karawek A; Nanocomposite Engineering Laboratory (NanoCEN), Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, Thailand., Kittipoom K; Nanocomposite Engineering Laboratory (NanoCEN), Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, Thailand., Tansuthepverawongse L; Nanocomposite Engineering Laboratory (NanoCEN), Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, Thailand., Kitjanukit N; Nanocomposite Engineering Laboratory (NanoCEN), Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, Thailand., Neamsung W; Nanocomposite Engineering Laboratory (NanoCEN), Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, Thailand., Lertthanaphol N; Nanocomposite Engineering Laboratory (NanoCEN), Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, Thailand., Chanthara P; Nanocomposite Engineering Laboratory (NanoCEN), Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, Thailand., Ratchahat S; Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, Thailand., Phadungbut P; Nanocomposite Engineering Laboratory (NanoCEN), Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, Thailand., Kim-Lohsoontorn P; Center of Excellence on Catalysis and Catalytic Reaction Engineering, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330, Thailand., Srinives S; Nanocomposite Engineering Laboratory (NanoCEN), Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, Thailand.
Jazyk: angličtina
Zdroj: Nanomaterials (Basel, Switzerland) [Nanomaterials (Basel)] 2023 Jan 12; Vol. 13 (2). Date of Electronic Publication: 2023 Jan 12.
DOI: 10.3390/nano13020320
Abstrakt: Carbon dioxide (CO 2 ) photoreduction to high-value products is a technique for dealing with CO 2 emissions. The method involves the molecular transformation of CO 2 to hydrocarbon and alcohol-type chemicals, such as methane and methanol, relying on a photocatalyst, such as titanium dioxide (TiO 2 ). In this research, TiO 2 nanosheets (TNS) were synthesized using a hydrothermal technique in the presence of a hydrofluoric acid (HF) soft template. The nanosheets were further composited with graphene oxide and doped with copper oxide in the hydrothermal process to create the copper-TiO 2 nanosheets/graphene oxide (CTNSG). The CTNSG exhibited outstanding photoactivity in converting CO 2 gas to methane and acetone. The production rate for methane and acetone was 12.09 and 0.75 µmol h -1 g cat -1 at 100% relative humidity, providing a total carbon consumption of 71.70 µmol g cat -1 . The photoactivity of CTNSG was attributed to the heterostructure interior of the two two-dimensional nanostructures, the copper-TiO 2 nanosheets and graphene oxide. The nanosheets-graphene oxide interfaces served as the n-p heterojunctions in holding active radicals for subsequent reactions. The heterostructure also directed the charge transfer, which promoted electron-hole separation in the photocatalyst.
Databáze: MEDLINE
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