Extending the Hammett correlation to mechanochemical reactions.
| Autor: | Vugrin L; Ruđer Bošković Institute, Bijenička c. 54, Zagreb 10000, Croatia. ivan.halasz@irb.hr., Carta M; Department of Mechanical, Chemical and Materials Engineering, University of Cagliari, via Marengo 2, Cagliari 09123, Italy. francesco.delogu@unica.it., Delogu F; Department of Mechanical, Chemical and Materials Engineering, University of Cagliari, via Marengo 2, Cagliari 09123, Italy. francesco.delogu@unica.it., Halasz I; Ruđer Bošković Institute, Bijenička c. 54, Zagreb 10000, Croatia. ivan.halasz@irb.hr. |
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| Jazyk: | angličtina |
| Zdroj: | Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2023 Feb 07; Vol. 59 (12), pp. 1629-1632. Date of Electronic Publication: 2023 Feb 07. |
| DOI: | 10.1039/d2cc06487a |
| Abstrakt: | Using Raman in situ monitoring and mechanochemistry-specific kinetic analysis, we find a correlation between the reaction probability and the Hammett constants in a model mechanochemical reaction of imine formation, indicating that the body of knowledge developed in physical-organic chemistry could be transferable to ball milling reactions in the solid state. |
| Databáze: | MEDLINE |
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