Ni-Catalyzed Regioselective Reductive 1,3-Dialkenylation of Alkenes.
| Autor: | Wickham LM; Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, United States., Dhungana RK; Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, United States., Giri R; Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, United States. |
|---|---|
| Jazyk: | angličtina |
| Zdroj: | ACS omega [ACS Omega] 2022 Dec 27; Vol. 8 (1), pp. 1060-1066. Date of Electronic Publication: 2022 Dec 27 (Print Publication: 2023). |
| DOI: | 10.1021/acsomega.2c06417 |
| Abstrakt: | Dicarbofunctionalization is an important efficient synthetic technique for adding two chemical moieties across an alkene. Here, a novel method of reductive dicarbofunctionalization has been developed using a single alkenyl triflate as the electrophile, combined with an unactivated alkene. The reaction does not require an external auxiliary and proceeds with complete regioselectivity. Competing Interests: The authors declare no competing financial interest. (© 2022 The Authors. Published by American Chemical Society.) |
| Databáze: | MEDLINE |
| Externí odkaz: |
|