Hydrazone-based boron difluoride complexes as triplet photosensitizers for singlet oxygen generation.

Autor: van Vliet S; Stratingh Institute for Chemistry, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, Groningen 9747 AG, The Netherlands., Hermens JGH; Stratingh Institute for Chemistry, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, Groningen 9747 AG, The Netherlands., Fu Y; Stratingh Institute for Chemistry, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, Groningen 9747 AG, The Netherlands., Pfeifer L; Stratingh Institute for Chemistry, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, Groningen 9747 AG, The Netherlands., Feringa BL; Stratingh Institute for Chemistry, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, Groningen 9747 AG, The Netherlands.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2023 Jan 19; Vol. 59 (7), pp. 884-887. Date of Electronic Publication: 2023 Jan 19.
DOI: 10.1039/d2cc05336e
Abstrakt: Due to the highly selective nature of singlet oxygen as an oxidant, it has received considerable interest in various areas of (organic) chemistry. Two green light activated hydrazone-based boron difluoride triplet photosensitizers possessing high quantum yields for 1 O 2 formation are reported. These photostable complexes are promising in applications in synthesis and catalysis.
Databáze: MEDLINE