| Autor: |
Liu Y; State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Gansu, Lanzhou 730000, China.; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China., Wu Y; State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Gansu, Lanzhou 730000, China.; Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering, Shandong Laboratory of Advanced Materials and Green Manufacturing, Yantai 264006, China.; Qingdao Centre of Resource Chemistry and New Materials, Shandong Qingdao 266100, China., Zhou F; State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Gansu, Lanzhou 730000, China. |
| Jazyk: |
angličtina |
| Zdroj: |
Langmuir : the ACS journal of surfaces and colloids [Langmuir] 2023 Jan 10; Vol. 39 (1), pp. 37-44. Date of Electronic Publication: 2022 Dec 22. |
| DOI: |
10.1021/acs.langmuir.2c03012 |
| Abstrakt: |
Research on polymer brushes (PBs) has aroused great interest due to their wide range of applications in lubrication, antifogging, antifouling, self-cleaning, antiadhesion, antibacterial effects, and so forth. However, the weak mechanical strength, especially the low bond strength between the PBs and the substrate surface, is a long-standing challenge for its practical applications, which is directly related to the service life of the PB surface. Fortunately, the imperfection of the PB surface was gradually solved by researchers by combining the action of the chemical and physical anchoring strength, and many shear-stable PB surfaces were developed. In this Perspective, we present recent developments in the studies of shear-stable PBs. Conventional strategies that altered the structure of PB chain methods, including increasing grafted density, cross-linking of PBs, cyclic PBs, and so forth, are introduced briefly. The systematic subsurface grafting of the polymer brush (SSPB) strategy was introduced emphatically. The SSPB method grafted PB into the subsurface with considerable depth and gave a robust and reusable PB layer, which provided an approach for tackling the shear-resistance issue. Besides, the robust hydrophobic poly(dimethylsiloxane) (PDMS) brush surface that lubricated itself in air was also introduced. Finally, we provide a synopsis and discuss the outlook of the shear-stable PB surface. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
|
