LaCo 1- x - y Cu x Ti y O 3 /KIT-6 perovskites: synthesis and catalytic behavior in syngas conversion to higher alcohols.

Autor: Dokuchits EV; Federal Research Center Boreskov Institute of Catalysis SB RAS, Akad. Lavrentieva Ave. 5, Novosibirsk 630090, Russia., Kardash TY; Federal Research Center Boreskov Institute of Catalysis SB RAS, Akad. Lavrentieva Ave. 5, Novosibirsk 630090, Russia., Larina TV; Federal Research Center Boreskov Institute of Catalysis SB RAS, Akad. Lavrentieva Ave. 5, Novosibirsk 630090, Russia., Bespalko YN; Federal Research Center Boreskov Institute of Catalysis SB RAS, Akad. Lavrentieva Ave. 5, Novosibirsk 630090, Russia., Minyukova TP; Federal Research Center Boreskov Institute of Catalysis SB RAS, Akad. Lavrentieva Ave. 5, Novosibirsk 630090, Russia.
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2023 Jan 03; Vol. 52 (2), pp. 409-420. Date of Electronic Publication: 2023 Jan 03.
DOI: 10.1039/d2dt03298h
Abstrakt: Highly dispersed LaCo 1- x - y Cu x Ti y O 3 /KIT-6 perovskites were synthesized by the citrate method with inert mesoporous KIT-6 addition. The KIT-6 matrix was removed by dissolution in 7% NaOH aqueous solution. The dispersity of perovskites probably varies depending on the largest cation and its content at the B position of the perovskite ABO3 structure. The Co S =2 3+ /Co S =0 3+ ratio increases with the increase in copper content and in the presence of Ti 4+ . It may be explained by the compensation of the distortion of the perovskite structure. The maximum syngas conversion is achieved at n Co / n Cu = 7/3. At a higher copper content, the activity of the samples decreases due to the formation of large copper particles (up to 40 nm) in the course of the reduction. The selectivity for alcohols increases with an increase in the proportion of copper and reaches maximum values at a ratio of n Co / n Cu close to 1. The distribution of alcohols is the same for all samples, except for LaCo 0.35 Cu 0.35 Ti 0.3 O 3 /KIT-6. It can be assumed that the synthesis of alcohols proceeds on bimetallic CoCu particles 3 nm in size and cobalt particles 4-6 nm in size, most likely enriched with copper on the surface.
Databáze: MEDLINE
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