Optimization via response surface methodology of palm kernel shell biochar for supplementary cementitious replacement.

Autor: Nusrat Aman AM; Department of Civil Engineering, University of Nottingham Malaysia, Jalan Broga, Semenyih, 43500, Selangor, Malaysia., Selvarajoo A; Department of Civil Engineering, University of Nottingham Malaysia, Jalan Broga, Semenyih, 43500, Selangor, Malaysia. Electronic address: Anurita.Selvarajoo@nottingham.edu.my., Lau TL; Department of Civil Engineering, University of Nottingham Malaysia, Jalan Broga, Semenyih, 43500, Selangor, Malaysia., Chen WH; Department of Aeronautics and Astronautics, National Cheng Kung University, Tainan, 701, Taiwan; Research Center for Smart Sustainable Circular Economy, Tunghai University, Taichung, 407, Taiwan; Department of Mechanical Engineering, National Chin-Yi University of Technology, Taichung, 411, Taiwan.
Jazyk: angličtina
Zdroj: Chemosphere [Chemosphere] 2023 Feb; Vol. 313, pp. 137477. Date of Electronic Publication: 2022 Dec 09.
DOI: 10.1016/j.chemosphere.2022.137477
Abstrakt: The use of sustainable materials in the construction industry has been on the rise recently. Studies have proven that the use of conventional concrete and its raw materials has a negative impact on the environment. Research on incorporating biochar as a supplementary cementitious material has been recently evolving and has shown that the attributes of biochar are highly affected by the pyrolysis parameters. These attributes have enhanced the properties of biochar concrete and mortar composite. This paper identifies the different physiochemical properties exhibited by palm kernel shell biochar through optimization by response surface methodology. Focusing on some of the properties of biochar that have proven beneficial when used as a cement replacement. Very limited research has used optimization tools for the production of biochar with the intention of using it as a cement substitute. Pyrolysis was conducted by a tubular furnace at different temperature ranges from 200 °C to 800 °C. The biomass and biochar have been analyzed with TGA and FESEM-EDX. The targeted biochar properties and selected responses are the yield, carbon, oxygen, silica, and potassium content. The optimized parameters obtained are 409 °C, 15 °C/min, 120 min with responses of 38.2% yield, 73.37% carbon, 25.48% oxygen, 0.39% potassium and 0.44% silica. Thermal properties of the palm kernel shell biochar affected by the pyrolysis factors such as temperature, heating rate and residence time have also been discussed. In conclusion, this study supports and encourages the use of palm waste, which is abundant in Malaysia, as a supplementary cementitious material to promote sustainable growth in construction.
Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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Databáze: MEDLINE