Effects of Na 2 CO 3 /Na 2 SiO 3 Ratio and Curing Temperature on the Structure Formation of Alkali-Activated High-Carbon Biomass Fly Ash Pastes.

Autor: Zhu C; Laboratory of Concrete Technology, Institute of Building Materials, Vilnius Gediminas Technical University, Linkmenų Str. 28, LT-08217 Vilnius, Lithuania., Pundienė I; Laboratory of Concrete Technology, Institute of Building Materials, Vilnius Gediminas Technical University, Linkmenų Str. 28, LT-08217 Vilnius, Lithuania., Pranckevičienė J; Laboratory of Concrete Technology, Institute of Building Materials, Vilnius Gediminas Technical University, Linkmenų Str. 28, LT-08217 Vilnius, Lithuania., Kligys M; Laboratory of Concrete Technology, Institute of Building Materials, Vilnius Gediminas Technical University, Linkmenų Str. 28, LT-08217 Vilnius, Lithuania.
Jazyk: angličtina
Zdroj: Materials (Basel, Switzerland) [Materials (Basel)] 2022 Nov 24; Vol. 15 (23). Date of Electronic Publication: 2022 Nov 24.
DOI: 10.3390/ma15238354
Abstrakt: This study explored unprocessed high-carbon biomass fly ash (BFA) in alkali-activated materials (AAM) with less alkaline Na 2 CO 3 as the activator. In this paper, the effects of the Na 2 CO 3 /Na 2 SiO 3 (C/S) ratio and curing temperature (40 °C and 20 °C) on the setting time, structure formation, product synthesis, and physical-mechanical properties of alkali-activated BFA pastes were systematically investigated. Regardless of curing temperature, increasing the C/S ratio increased the density and compressive strength of the sample while a decrease in water absorption. The higher the curing temperature, the faster the structure evolution during the BFA-based alkaline activation synthesis process and the higher the sample's compressive strength. According to XRD and TG/DTA analyses, the synthesis of gaylussite and C-S-H were observed in the sample with an increasing C/S ratio. The formation of the mentioned minerals contributes to the compressive strength growth of alkali-activated BFA pastes with higher C/S ratios. The findings of this study contribute to the applicability of difficult-to-recycle waste materials such as BFA and the development of sustainable BFA-based AAM.
Databáze: MEDLINE
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