Persulfate-promoted synthesis of biphenyl compounds in water from biomass-derived triacetic acid lactone.
| Autor: | Duarte Ortin GG; Department of Organic Chemistry, Institute of Chemistry, University of Campinas, P.O. Box 6154, Campinas, SP 13084-862, Brazil. hoffman@unicamp.br., Salles AG Jr; Department of Organic Chemistry, Institute of Chemistry, University of Campinas, P.O. Box 6154, Campinas, SP 13084-862, Brazil. hoffman@unicamp.br. |
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| Jazyk: | angličtina |
| Zdroj: | Organic & biomolecular chemistry [Org Biomol Chem] 2022 Dec 07; Vol. 20 (47), pp. 9292-9297. Date of Electronic Publication: 2022 Dec 07. |
| DOI: | 10.1039/d2ob01900k |
| Abstrakt: | A metal-free, persulfate-promoted route in water to access substituted biphenyl compounds is described. In our approach, the biomass-derived triacetic acid lactone (TAL) and phenylacetylenes are employed to generate targeted products in high yields and regioselectivity. The present method contributes to the green synthesis initiative to harness renewable biomass-derived compounds in environmentally friendly methodologies. |
| Databáze: | MEDLINE |
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