Development of a modular photoreactor for the upscaling of continuous flow photochemistry.
| Autor: | Hermens JGH; Stratingh Institute for Chemistry, Advanced Research Center Chemical Building Blocks Consortium (ARC CBBC), University of Groningen Nijenborgh 4 9747 AG Groningen The Netherlands b.l.feringa@rug.nl., Lepage ML; Stratingh Institute for Chemistry, Advanced Research Center Chemical Building Blocks Consortium (ARC CBBC), University of Groningen Nijenborgh 4 9747 AG Groningen The Netherlands b.l.feringa@rug.nl., Kloekhorst A; Hanze University of Applied Sciences Zernikeplein 11 9747 AS Groningen The Netherlands., Keller E; Hanze University of Applied Sciences Zernikeplein 11 9747 AS Groningen The Netherlands., Bloem R; Hanze University of Applied Sciences Zernikeplein 11 9747 AS Groningen The Netherlands., Meijer M; Hanze University of Applied Sciences Zernikeplein 11 9747 AS Groningen The Netherlands., Feringa BL; Stratingh Institute for Chemistry, Advanced Research Center Chemical Building Blocks Consortium (ARC CBBC), University of Groningen Nijenborgh 4 9747 AG Groningen The Netherlands b.l.feringa@rug.nl. |
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| Jazyk: | angličtina |
| Zdroj: | Reaction chemistry & engineering [React Chem Eng] 2022 Sep 28; Vol. 7 (11), pp. 2280-2284. Date of Electronic Publication: 2022 Sep 28 (Print Publication: 2022). |
| DOI: | 10.1039/d2re00310d |
| Abstrakt: | The upscaling of biphasic photochemical reactions is challenging because of the inherent constraints of liquid-gas mixing and light penetration. Using semi-permeable coaxial flow chemistry within a modular photoreactor, the photooxidation of the platform chemical furfural was scaled up to produce routinely 29 gram per day of biobased building block hydroxybutenolide, a precursor to acrylate alternatives. Competing Interests: There are no conflicts to declare. (This journal is © The Royal Society of Chemistry.) |
| Databáze: | MEDLINE |
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