catena -Poly[[bis-(1 H -indole-5-carboxyl-ato-κ 2 O , O ')zinc(II)]-μ-4,4'-azobi-pyridine-κ 2 N 1 : N 1' ].

Autor: Sathya U; Centre for Research and Development, PRIST Deemed to be University, Thanjavur, 613 403, Tamil Nadu, India., Nirmal Ram JS; Centre for Research and Development, PRIST Deemed to be University, Thanjavur, 613 403, Tamil Nadu, India., Gomathi S; Department of Chemistry, Periyar Maniammai Institute of Science and Technology, Thanjavur 613 403, Tamil Nadu, India., Jegan Jennifer S; X-ray Crystallography Unit, School of Physics, University Sains Malaysia, 11800, USM, Penang, Malaysia., Abdul Razak I; X-ray Crystallography Unit, School of Physics, University Sains Malaysia, 11800, USM, Penang, Malaysia.
Jazyk: angličtina
Zdroj: IUCrData [IUCrdata] 2021 May 21; Vol. 6 (Pt 5), pp. x210522. Date of Electronic Publication: 2021 May 21 (Print Publication: 2021).
DOI: 10.1107/S2414314621005228
Abstrakt: The asymmetric unit of the title coordination polymer [Zn(C 9 H 6 NO 2 ) 2 (C 10 H 8 N 4 )] n , consists of one Zn II cation, one bidentate 1 H -indole-5-carboxyl-ate (I5C) anion and half of a 4,4'-azobi-pyridine (Abpy) neutral ligand. In the coordination polyhedron, the Zn II ion adopts a distorted octa-hedral geometry. The coordination polymer is stabilized by a combination of N-H⋯O and C-H⋯π inter-actions, which leads to the formation of wave-like two-dimensional coordination polymeric layers.
(© Sathya et al. 2021.)
Databáze: MEDLINE
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