A neutral vicinal silylene/phosphane supported six-membered C 2 PSiAu 2 ring and a silver(I) complex.

Autor:	Nazish M; Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, Göttingen, 37077, Germany. hroesky@gwdg.de., Bai H; Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, 211816, China., Legendre CM; Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, Göttingen, 37077, Germany. hroesky@gwdg.de., Herbst-Irmer R; Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, Göttingen, 37077, Germany. hroesky@gwdg.de., Zhao L; Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, 211816, China., Stalke D; Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, Göttingen, 37077, Germany. hroesky@gwdg.de., Roesky HW; Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, Göttingen, 37077, Germany. hroesky@gwdg.de.
Jazyk:	angličtina
Zdroj:	Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2022 Nov 15; Vol. 58 (91), pp. 12704-12707. Date of Electronic Publication: 2022 Nov 15.
DOI:	10.1039/d2cc04163d
Abstrakt:	This work presents the different coordination nature of the bidentate ligand towards gold and silver complexes. The reaction of 1 with AuClSMe 2 in dichloromethane resulted in two gold atoms containing six-membered ring PhC(N t Bu) 2 Si-Au⋯Au-PPh 2 C 6 H 4 (2). Compound 2 exhibits intramolecular aurophilic interaction (2.9987(7) Å), which is further supported by quantum chemical calculations. Moreover, the reduction of aluminium adduct 3 with AgSbF 6 affords insertion of silver cation [{PhC(N t Bu) 2 SiF 2 }-C 6 H 4 (PPh 2 )-Ag-(PPh 2 )C 6 H 4 {PhC(N t Bu) 2 SiF 2 }]AlCl 4 - (4) between two phosphane. In compound 4 only two P(III) of two molecules of 1 coordinates to Ag(I), while two Si(II) remains uncoordinated and gives oxidative addition of Fluorine.
Databáze:	MEDLINE
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