| Autor: |
Ghasemzadeh K; Faculty of Chemical Engineering, Urmia University of Technology, Urmia 57166-93187, Iran., Ghahremani M; Faculty of Chemical Engineering, Urmia University of Technology, Urmia 57166-93187, Iran., Jalilnejad E; Faculty of Chemical Engineering, Urmia University of Technology, Urmia 57166-93187, Iran., Yousefi Amiri T; Chemical Engineering Department, University of Zanjan, Zanjan 45371-38791, Iran., Basile A; Hydrogenia S.r.l., Via Roma, n. 8/2, 16121 Genoa, Italy.; Department of Engineering, University Campus Bio-Medico of Rome, Via Alvaro del Portillo n. 21, 00128 Rome, Italy. |
| Abstrakt: |
A detailed numerical study of ethyl levulinate (EtLA) production with levulinic acid (LA) and ethanol (Et) in a multi-bed traditional reactor (MB-TR) and a silica-based and polymeric multi-bed pervaporation membrane reactors (MB-PVMR) was conducted and the efficiency of each design was studied under different operation conditions. Due to water production in the EtLA production process, water removal by a pervaporation system may improve process performance. Our results showed that MB-PVMR had higher performance compared with MB-TR. In addition, the silica membrane was more effective in water removal compared with the polymeric membrane. Therefore, higher LA conversion was achievable by a silica-based multi-bed pervaporation membrane reactor (SMB-PVMR). All the results were evaluated for percentage of water removal and LA conversion, based on variations in the Et/LA molar ratio, feed molar flow, reaction zone temperature, and catalyst loading. The results showed that water removal was higher than 95% and LA conversion of about 95% was attained by SMB-PVMR. |
