Metals in seston from Cabo Frio Bay, a region under the influence of upwelling in SE-Brazil.

Autor: Kütter VT; Faculdade de Oceanografia, Instituto de Geociências, Universidade Federal do Pará, Augusto Correa nº1, Belém, PA, 66075-110, Brazil. kutter@ufpa.br., Albuquerque ALS; Departamento de Geoquímica, Instituto de Química, Universidade Federal Fluminense, Outeiro de São João Batista s/n, Niterói, RJ, 24020-141, Brazil., Moreira JC; Centro de Estudos da Saúde do Trabalhador e Ecologia Humana (CESTEH), Escola Nacional de Saúde Pública (ENSP), FIOCRUZ, Leopoldo Bulhões nº 1480, Rio de Janeiro, RJ, 21041-210, Brazil., de Almeida EV; Laboratório de Carcinologia, Instituto de Biologia, Universidade Federal do Rio de Janeiro, Av. Carlos Chagas Filho, n. 373, Rio de Janeiro, RJ, 21941-902, Brazil., Aguilera O; Laboratório de Paleoecologia e Mudanças Globais, Instituto de Biologia, Universidade Federal Fluminense, Campus Gragoatá bloco M, Niterói, RJ, 24210-201, Brazil., Filho EVS; Departamento de Geoquímica, Instituto de Química, Universidade Federal Fluminense, Outeiro de São João Batista s/n, Niterói, RJ, 24020-141, Brazil.
Jazyk: angličtina
Zdroj: Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine [Biometals] 2023 Feb; Vol. 36 (1), pp. 49-66. Date of Electronic Publication: 2022 Oct 25.
DOI: 10.1007/s10534-022-00457-7
Abstrakt: This study, performed during 2003-2005 and 2008-2009, investigated metals (Al, Fe, Ba, Zn, Mn, Cr, Cu, Ni, Cd) content in seston at Cabo Frio Bay, SE-Brazil. This study may serve as a baseline of seston metal distribution to guide biogeochemical and ecological models. The seston fractions (> 20 µm, > 64 µm, > 100 µm, and > 150 µm) were sampled in sub-surface horizontal hauls. Metals were determined by ICP-MS. The metals range: Al (62.5-56,867.6 µg g -1 ), Fe (23.5-25,384.0 µg g -1 ), Mn (2.7-336.8 µg g -1 ), Ba (< 0.005-356.3 µg g -1 ), Zn (0.5-94.2 µg g -1 ), Cr (0.7-35.5 µg g -1 ), Cu (4.3-41.7 µg g -1 ), Ni (< 0.005-19.1 µg g -1 ) and Cd (< 0.0004-2.4 µg g -1 ). Aluminium, Fe, Mn, Ba, and Zn showed significant differences (p < 0.05) between the seston fraction. The results obtained in this study suggest that the elements (Fe, Mn, Ba) in the seston were strongly influenced by the abiogenic source. In contrast, Zn, Cd, Cu, Cr, and Ni can be biogenic/anthropogenic sources. The significant positive linear correlation of Zn:P, Cd:P, and Cu:P can indicate an intracellular concentration higher than the external adsorption in the plankton community.
(© 2022. The Author(s), under exclusive licence to Springer Nature B.V.)
Databáze: MEDLINE