Electric-field-induced coupling of aryl iodides with a nickel(0) complex.
| Autor: | Orchanian NM; Department of Chemistry, Columbia University, New York, New York 10027, USA. mls2064@columbia.edu., Guizzo S; Department of Applied Physics and Mathematics, Columbia University, New York, New York 10027, USA., Steigerwald ML; Department of Chemistry, Columbia University, New York, New York 10027, USA. mls2064@columbia.edu., Nuckolls C; Department of Chemistry, Columbia University, New York, New York 10027, USA. mls2064@columbia.edu., Venkataraman L; Department of Chemistry, Columbia University, New York, New York 10027, USA. mls2064@columbia.edu.; Department of Applied Physics and Mathematics, Columbia University, New York, New York 10027, USA. |
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| Jazyk: | angličtina |
| Zdroj: | Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2022 Nov 10; Vol. 58 (90), pp. 12556-12559. Date of Electronic Publication: 2022 Nov 10. |
| DOI: | 10.1039/d2cc03671a |
| Abstrakt: | The formation of carbon-carbon bonds with transition metal reagents serves as a cornerstone of organic synthesis. Here, we show that the reactivity of an otherwise kinetically inert transition metal complex can be induced by an external electric field to affect a coupling reaction. These results highlight the importance of electric field effects in reaction chemistry and offers a new strategy to modulate organometallic reactivity. |
| Databáze: | MEDLINE |
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