Ozone-3,6-dihydroxynaphtha-2,7-disulphonate chemiluminescence system is used for online ozone detection.

Autor: Xiong Y; School of Chemical Engineering, Sichuan University of Science & Engineering, 180 Xueyuan Street, Huixing Road, Zigong City, China., Wang Z; Dezhou University, 566 West University Road, Decheng District, Dezhou City, Shandong Province, China., Tang L; School of Chemical Engineering, Sichuan University of Science & Engineering, 180 Xueyuan Street, Huixing Road, Zigong City, China., Chen Q; School of Chemical and Environmental Engineering, Sichuan University of Science & Engineering, 180 Xueyuan Street, Huixing Road, Zigong City, China., Feng Y; School of Chemical and Environmental Engineering, Sichuan University of Science & Engineering, 180 Xueyuan Street, Huixing Road, Zigong City, China., Xie Z; School of Chemical Engineering, Sichuan University of Science & Engineering, 180 Xueyuan Street, Huixing Road, Zigong City, China., Fu D; School of Chemical Engineering, Sichuan University of Science & Engineering, 180 Xueyuan Street, Huixing Road, Zigong City, China.
Jazyk: angličtina
Zdroj: Luminescence : the journal of biological and chemical luminescence [Luminescence] 2023 Jan; Vol. 38 (1), pp. 12-18. Date of Electronic Publication: 2022 Dec 04.
DOI: 10.1002/bio.4393
Abstrakt: The chemiluminescence (CL) reaction between ozone and 3,6-dihydroxynaphtha-2,7-disulphonate (DNDS) was found under alkaline conditions. Therefore, a novel CL system for ozone detection was established. The CL signal of the CL system is weak, and the CL signal is enhanced by adding nonionic surfactants. It was found that adding 16.4 g/l Triton X-100 can enhance the CL signal. The CL reagent activated by ultraviolet (UV) light produced a CL signal was nearly 10 times stronger than the CL reagent not activated by UV light; the CL signal was enhanced by adding 8 g/l NaHCO 3 to the CL reagent irradiated by UV light. Through the optimization of these test conditions, a high-selectivity, high-sensitivity online detection method for ozone CL was established. The linear range was 0.5-150 ppbv, and the limit of detection (LOD) was 0.092 ppbv (S/N = 3).
(© 2022 John Wiley & Sons Ltd.)
Databáze: MEDLINE