Triazine based eccentric Piedfort units towards a single source hydrogen bonded network.

Autor: Mehrotra S; Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India. raja@iitk.ac.in., Raje S; Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India. raja@iitk.ac.in., Jain AK; Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India. raja@iitk.ac.in., Butcher RJ; Department of Chemistry, Howard University, Washington, D.C. 20059, USA., Angamuthu R; Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India. raja@iitk.ac.in.; Department of Sustainable Energy Engineering, Indian Institute of Technology Kanpur, Kanpur 208016, India.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2022 Oct 20; Vol. 58 (84), pp. 11815-11818. Date of Electronic Publication: 2022 Oct 20.
DOI: 10.1039/d2cc03327e
Abstrakt: Herein we report a hydrogen-bonded three-dimensional network originating from a single source precursor, sym -triisopropylaminotriazine, that is both a donor and an acceptor of hydrogen bonds. The C 3h symmetric design allowed the formation of intermolecular hydrogen bonds leading to helices in all three directions. The eccentric Piedfort units present in the framework with a distance of 8.15 Å between the two triazine rings allowed the CHCl 3 guest to be parked.
Databáze: MEDLINE
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