Development of an ultrasensitive molecularly imprinted poly-(ortho-phenylenediamine) based sensor for the determination of melamine adulteration in milk and infant formula.

Autor: Heydarian-Dehkordi N; Department of Food Hygiene and Quality Control Faculty of Veterinary Medicine Shahrekord University Shahrekord Iran., Saei-Dehkordi SS; Department of Food Hygiene and Quality Control Faculty of Veterinary Medicine Shahrekord University Shahrekord Iran., Izadi Z; Department of Mechanical Engineering of Biosystems Faculty of Agriculture Shahrekord University Shahrekord Iran., Ghasemi-Varnamkhasti M; Department of Mechanical Engineering of Biosystems Faculty of Agriculture Shahrekord University Shahrekord Iran.
Jazyk: angličtina
Zdroj: Food science & nutrition [Food Sci Nutr] 2022 May 16; Vol. 10 (9), pp. 3154-3164. Date of Electronic Publication: 2022 May 16 (Print Publication: 2022).
DOI: 10.1002/fsn3.2914
Abstrakt: A sensitive molecularly imprinted poly-(ortho-phenylenediamine) electrochemical sensor was fabricated for selective melamine detection in milk and infant formula. The pencil graphite electrode (PGE) was modified by deposition of Au nanoparticles and reduced graphene oxide (RGO) on its surface. The fabrication of the electrode in various stages was monitored using cyclic voltammetry. The immobilized RGO, MIP, and gold nanoparticles on the PGE surface were morphologically characterized by field-emission scanning electron microscopy (FESEM). Under the optimized conditions, the linear range and the limit of detection (LOD) were 10 -17 -10 -8  M and 2.64 × 10 -16  M (S/N = 3), respectively. The prepared sensor exhibited a good reproducibility and repeatability response. The recovery range of melamine-spiked milk and infant formula was 92.7%-103.9% and 93.5%-105.8%, respectively. The sensor could apply successfully for melamine determination in milk and infant formula samples.
Competing Interests: The authors declare that there are no conflicts of interest.
(© 2022 The Authors. Food Science & Nutrition published by Wiley Periodicals LLC.)
Databáze: MEDLINE
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