At Least 10-fold Higher Lubricity of Molecularly Thin D 2 O vs H 2 O Films at Single-Layer Graphene-Mica Interfaces.

Autor: Lin H; Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstrasse 15, Berlin 12489, Germany., Habibova L; Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstrasse 15, Berlin 12489, Germany., Rauf A; Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstrasse 15, Berlin 12489, Germany., Cojal González JD; Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstrasse 15, Berlin 12489, Germany., Severin N; Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstrasse 15, Berlin 12489, Germany., Kirstein S; Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstrasse 15, Berlin 12489, Germany., Sokolov IM; Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstrasse 15, Berlin 12489, Germany., Rabe JP; Department of Physics & IRIS Adlershof, Humboldt-Universität zu Berlin, Newtonstrasse 15, Berlin 12489, Germany.
Jazyk: angličtina
Zdroj: Nano letters [Nano Lett] 2022 Oct 12; Vol. 22 (19), pp. 7761-7767. Date of Electronic Publication: 2022 Sep 28.
DOI: 10.1021/acs.nanolett.2c01425
Abstrakt: Interfacial water is a widespread lubricant down to the nanometer scale. We investigate the lubricities of molecularly thin H 2 O and D 2 O films confined between mica and graphene, via the relaxation of initially applied strain in graphene employing Raman spectroscopy. Surprisingly, the D 2 O films are at least 1 order of magnitude more lubricant than H 2 O films, despite the similar bulk viscosities of the two liquids. We propose a mechanism based on the known selective permeation of protons vs deuterons through graphene. Permeated protons and left behind hydroxides may form ion pairs clamping across the graphene sheet and thereby hindering the graphene from sliding on the water layer. This explains the lower lubricity but also the hindering diffusivity of the water layer, which yields a high effective viscosity in accordance with findings in dewetting experiments. Our work elucidates an unexpected effect and provides clues to the behavior of graphene on hydrous surfaces.
Databáze: MEDLINE
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