| Autor: |
Diaz-Rodriguez RM; Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada. m.murugesu@uottawa.ca., Kitos AA; Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada. m.murugesu@uottawa.ca., Murugesu M; Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada. m.murugesu@uottawa.ca. |
| Jazyk: |
angličtina |
| Zdroj: |
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2022 Oct 04; Vol. 51 (38), pp. 14420-14428. Date of Electronic Publication: 2022 Oct 04. |
| DOI: |
10.1039/d2dt02615e |
| Abstrakt: |
Herein we detail the straightforward and scalable synthesis of sodium and potassium complexes of the 2,5-bis( tert -butyldimethylsilyl)-3,4-diphenylplumbolyl dianion (Pbl TBS,Ph ). Their solid-state structures were found to comprise either monomeric solvates or coordination polymers depending on the alkali metal ion and crystallization medium. These complexes were readily prepared with high yields and purity compared to known routes to the dilithium congener of Pbl TBS,Ph and are well-positioned to serve as convenient precursors for salt metathesis-type reactions leading to metal complexes of the understudied Pbl TBS,Ph ligand. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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