| Autor: |
Lai DS; Faculty of Chemical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Arau 02600, Perlis, Malaysia.; Biomedical and Nanotechnology Research Group, Center of Excellent Geopolymer and Green Technology (CEGeoTech), Universiti Malaysia Perlis (UniMAP), Arau 02600, Perlis, Malaysia., Osman AF; Faculty of Chemical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Arau 02600, Perlis, Malaysia.; Biomedical and Nanotechnology Research Group, Center of Excellent Geopolymer and Green Technology (CEGeoTech), Universiti Malaysia Perlis (UniMAP), Arau 02600, Perlis, Malaysia., Adnan SA; Faculty of Chemical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Arau 02600, Perlis, Malaysia.; Biomedical and Nanotechnology Research Group, Center of Excellent Geopolymer and Green Technology (CEGeoTech), Universiti Malaysia Perlis (UniMAP), Arau 02600, Perlis, Malaysia., Ibrahim I; Faculty of Chemical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Arau 02600, Perlis, Malaysia.; Biomedical and Nanotechnology Research Group, Center of Excellent Geopolymer and Green Technology (CEGeoTech), Universiti Malaysia Perlis (UniMAP), Arau 02600, Perlis, Malaysia., Ahmad Salimi MN; Faculty of Chemical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Arau 02600, Perlis, Malaysia.; Biomedical and Nanotechnology Research Group, Center of Excellent Geopolymer and Green Technology (CEGeoTech), Universiti Malaysia Perlis (UniMAP), Arau 02600, Perlis, Malaysia., Alrashdi AA; Chemistry Department, Umm Al-Qura University, Al-Qunfudah University College, Al-Qunfudah Center for Scientific Research (QCSR), Al Qunfudah 21962, Saudi Arabia. |
| Abstrakt: |
Recently, hybrid fillers have been widely used to improve the properties of biopolymers. The synergistic effects of the hybrid fillers can have a positive impact on biopolymers, including thermoplastic corn starch film (TPCS). In this communication, we highlight the effectiveness of hybrid fillers in inhibiting the aging process of TPCS. The TPCS, thermoplastic corn starch composite films (TPCS-C), and hybrid thermoplastic corn starch composite film (TPCS-HC) were stored for 3 months to study the effect of hybrid filler on the starch retrogradation. TPCS-C and TPCS-HC were prepared by casting method with 5 wt% of fillers: nanocellulose (NC) and bentonite (BT). The alteration of the mechanical properties, aging behavior, and crystalline structure of the films were analyzed through the tensile test, Fourier transform infrared (FTIR), X-ray diffraction (XRD), differential scanning calorimetry (DSC), and water absorption analysis. The obtained data were correlated to each other to analyze the retrogradation of the TPCS, which is the main factor that contributes to the aging process of the biopolymer. Results signify that incorporating the hybrid filler (NC + BT) in the TPCS/4BT1NC films has effectively prevented retrogradation of the starch molecules after being stored for 3 months. On the contrary, the virgin TPCS film showed the highest degree of retrogradation resulting in a significant decrement in the film's flexibility. These findings proved the capability of the green hybrid filler in inhibiting the aging of the TPCS. |
