Improving the Stability and Efficiency of Perovskite Solar Cells by a Bidentate Anilinium Salt.

Autor:	Scalon L; Institute of Chemistry, University of Campinas, Campinas, São Paulo 13083-970, Brazil., Szostak R; Institute of Chemistry, University of Campinas, Campinas, São Paulo 13083-970, Brazil., Araújo FL; Institute of Chemistry, University of Campinas, Campinas, São Paulo 13083-970, Brazil., Adriani KF; São Carlos Institute of Chemistry, University of São Paulo, São Carlos, São Paulo 13560-970, Brazil., Silveira JFRV; São Carlos Institute of Chemistry, University of São Paulo, São Carlos, São Paulo 13560-970, Brazil., Oliveira WXC; Department of Chemistry, Federal University of Minas Gerais, Belo Horizonte, Minas Gerais 31270-901, Brazil., Da Silva JLF; São Carlos Institute of Chemistry, University of São Paulo, São Carlos, São Paulo 13560-970, Brazil., Oliveira CC; Institute of Chemistry, University of Campinas, Campinas, São Paulo 13083-970, Brazil., Nogueira AF; Institute of Chemistry, University of Campinas, Campinas, São Paulo 13083-970, Brazil.
Jazyk:	angličtina
Zdroj:	JACS Au [JACS Au] 2022 May 04; Vol. 2 (6), pp. 1306-1312. Date of Electronic Publication: 2022 May 04 (Print Publication: 2022).
DOI:	10.1021/jacsau.2c00151
Abstrakt:	We report improvement in the perovskite solar cell efficiency and stability after passivation with an organic molecule decorated with two anilinium cations. We compare this salt with its neutral analog and found that the change in the electron density distribution upon protonation and the presence of the halide anion are key to explaining the better passivation ability of the salt. In addition, we show that the counteranion has a significant impact on the performance of the device. Competing Interests: The authors declare no competing financial interest. (© 2022 The Authors. Published by American Chemical Society.)
Databáze:	MEDLINE
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