Importance of the polarity on nanostructured silica materials to optimize the hydrolytic condensation with molecules related to CO 2 adsorption.

Autor: Medina-Juárez O; Departamento de Química, Universidad Autónoma Metropolitana, CDMX, Iztapalapa, 09310, México. mjyuyu@gmail.com., Rangel-Vázquez I; Departamento de Química, Universidad Autónoma Metropolitana, CDMX, Iztapalapa, 09310, México., Ojeda-López R; Departamento de Química, Universidad Autónoma Metropolitana, CDMX, Iztapalapa, 09310, México.; Departamento de Engenharia Química, Universidade Federal Do Ceará, Fortaleza, CE, 60455-760, Brazil., García-Sánchez MÁ; Departamento de Química, Universidad Autónoma Metropolitana, CDMX, Iztapalapa, 09310, México., Rojas-González F; Departamento de Química, Universidad Autónoma Metropolitana, CDMX, Iztapalapa, 09310, México.
Jazyk: angličtina
Zdroj: Environmental science and pollution research international [Environ Sci Pollut Res Int] 2022 Aug; Vol. 29 (39), pp. 58472-58483. Date of Electronic Publication: 2022 Jul 01.
DOI: 10.1007/s11356-022-21540-z
Abstrakt: The present work reports the changes for the mesoporous materials SBA-15 and KIT-6 associated with the structural, textural, and chemical properties when they are subjected to thermo-alkaline treatment. Despite the fact that the silica supports have not a strong affinity for CO 2 adsorption, the adsorption enthalpy profiles (ΔH ads ) reported that the substrates subjected to the thermo-alkaline treatment (S15H and K6H) have a greater energetic affinity towards CO 2 capture if compared to the precursory solids (S15 and K6). The ΔH ads is - 26.7 kJ mol -1 at 0.15 mmol g -1 by supported S15H and K6H while the ΔH ads is - 20. 7 kJ mol -1 and - 18.7 kJ mol -1 by K6 and S15, respectively, at the same CO 2 coverage. Furthermore, the CO 2 adsorption performances by the hydrolytic condensation between silica supports and the N´- (3-trimethoxysilylpropyl)diethylenetriamine (NAEPTES) or 3-aminopropiltriethoxysilane (APTES) are presented and it can be seen that the best performer for CO 2 adsorption is reported for the S15HN since it is able to absorb 0.93 mmol at 0.15 atm at 318 K. Thereby, the outcomes show that the effects of porous curvature and the magnitude of the amine species are parameters to be considered, as well as the thermo-alkaline treatment, in order to improve the subsequent surface reactions on silica supports. The materials were characterized by XRD, TEM, and N 2 adsorption at 77 K, NIR, and pyridine thermodesorption using Fourier Transform Infrared Spectroscopy (FTIR-Py), NMR for 29 Si and 13 C, DSC, and CO 2 adsorption.
(© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)
Databáze: MEDLINE
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