Palladium-Catalyzed Organic Reactions Involving Hypervalent Iodine Reagents.

Autor: Shetgaonkar SE; Chemistry Division, School of Advanced Sciences (SAS), Vellore Institute of Technoloy-Chennai, Chennai 600127, Tamil Nadu, India., Mamgain R; Chemistry Division, School of Advanced Sciences (SAS), Vellore Institute of Technoloy-Chennai, Chennai 600127, Tamil Nadu, India., Kikushima K; College of Pharmaceutical Sciences, Ritsumeikan University, 1-1-1 Nojihigashi, Kusatsu 525-0058, Shiga, Japan., Dohi T; College of Pharmaceutical Sciences, Ritsumeikan University, 1-1-1 Nojihigashi, Kusatsu 525-0058, Shiga, Japan., Singh FV; Chemistry Division, School of Advanced Sciences (SAS), Vellore Institute of Technoloy-Chennai, Chennai 600127, Tamil Nadu, India.
Jazyk: angličtina
Zdroj: Molecules (Basel, Switzerland) [Molecules] 2022 Jun 17; Vol. 27 (12). Date of Electronic Publication: 2022 Jun 17.
DOI: 10.3390/molecules27123900
Abstrakt: The chemistry of polyvalent iodine compounds has piqued the interest of researchers due to their role as important and flexible reagents in synthetic organic chemistry, resulting in a broad variety of useful organic molecules. These chemicals have potential uses in various functionalization procedures due to their non-toxic and environmentally friendly properties. As they are also strong electrophiles and potent oxidizing agents, the use of hypervalent iodine reagents in palladium-catalyzed transformations has received a lot of attention in recent years. Extensive research has been conducted on the subject of C-H bond functionalization by Pd catalysis with hypervalent iodine reagents as oxidants. Furthermore, the iodine(III) reagent is now often used as an arylating agent in Pd-catalyzed C-H arylation or Heck-type cross-coupling processes. In this article, the recent advances in palladium-catalyzed oxidative cross-coupling reactions employing hypervalent iodine reagents are reviewed in detail.
Databáze: MEDLINE
Externí odkaz:
Nepřihlášeným uživatelům se plný text nezobrazuje