Living supramolecular polymerization of an amphiphilic aza-BODIPY dye realized by water-assisted kinetic trapping.

Autor: Liu Y; School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China. zjchen@tju.edu.cn., Pan H; School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China. zjchen@tju.edu.cn., Yuan S; School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China. zjchen@tju.edu.cn., Ding J; School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China. zjchen@tju.edu.cn., Jiang Y; School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China. zjchen@tju.edu.cn., Ren XK; School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China. zjchen@tju.edu.cn.; The National Collaborative Innovation Centre of Chemical Science and Engineering (Tianjin), 300072, China., Chen Z; School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China. zjchen@tju.edu.cn.; The National Collaborative Innovation Centre of Chemical Science and Engineering (Tianjin), 300072, China.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2022 Jul 07; Vol. 58 (55), pp. 7662-7665. Date of Electronic Publication: 2022 Jul 07.
DOI: 10.1039/d2cc02437c
Abstrakt: The kinetic assembly pathways of a newly synthesized amphiphilic aza-BODIPY dye 1 were tuned by using H 2 O as a co-solvent in MeOH. Accordingly, the biphasic aggregation pathways resulting in kinetically-trapped and thermodynamically stable aggregates of 1 were established and the multiple cyclic seeded living supramolecular polymerization of this dye was realized.
Databáze: MEDLINE