| Autor: |
Martinelli A; SPIN-CNR, Corso Perrone 24, 16152 Genova, Italy., Ray A; Nanochemistry Department, Istituto Italiano di Tecnologia, Via Morego 30, 16163 Genova, Italy., Abdelhady AL; Nanochemistry Department, Istituto Italiano di Tecnologia, Via Morego 30, 16163 Genova, Italy., Locardi F; Dipartimento di Chimica e Chimica Industriale, Universitá degli Studi di Genova, Via Dodecaneso 31, 16146 Genova, Italy. |
| Jazyk: |
angličtina |
| Zdroj: |
Acta crystallographica Section B, Structural science, crystal engineering and materials [Acta Crystallogr B Struct Sci Cryst Eng Mater] 2022 Jun 01; Vol. 78 (Pt 3 Pt 2), pp. 425-435. Date of Electronic Publication: 2022 Apr 21. |
| DOI: |
10.1107/S2052520622002438 |
| Abstrakt: |
The crystal structures of (CH 3 NH 3 ) 2 Cu(Cl 1-x Br x ) 4 compounds have been investigated by means of synchrotron powder X-ray diffraction and pair distribution function analysis at room temperature. As a result, new insights are gained about the structural properties of these compounds, suggesting a monoclinic symmetry (space group No. 14: P2 1 /c - C_{2h}^{5}) induced by the co-operative orbital ordering produced by the Jahn-Teller distortion characterizing the 3d 9 Cu 2+ ion. In contrast to previous studies, a significant amount of vacancies is found at halogen positions, a feature that can be likely ascribed to the synthesis technique adopted in the present study. Br atoms preferentially occupy axial positions, likely on account of reduced steric hindrance at these sites. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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