| Autor: |
Verchenko VY; Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia.; National Institute of Chemical Physics and Biophysics, 12618 Tallinn, Estonia., Stepanova AV; Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia., Bogach AV; Prokhorov General Physics Institute of the Russian Academy of Sciences, 119991 Moscow, Russia., Mironov AV; Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia., Shevelkov AV; Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia. |
| Abstrakt: |
Transition metal-based layered compounds with van der Waals gaps between the structural layers are a rich source of magnetic materials for spintronic applications. Bulk crystals can be cleaved, providing high-quality two-dimensional nanomaterials, which are promising for the manipulation of spins in spintronic devices and low power quantum logic interfaces. The layered van der Waals telluride Fe 5 AsTe 2 can be synthesized by the high-temperature reaction of elements. In the crystal structure, Fe-rich structural layers with the composition of Fe 4.58(4) AsTe 2 are separated by the van der Waals gaps with no atoms in the interstitial region. Crystal growth employing chemical vapor transport reactions yields bulk cleavable crystals, which exhibit weak inherent ferromagnetism below the Curie temperature of T C = 48 K. In the ordered state, the magnetization shows a dual-slope behavior in low magnetic fields, indicating the compensated or canted nature of magnetism. Magnetic susceptibility and magnetization measurements reveal perpendicular magnetic anisotropy. The large Rhodes-Wohlfarth ratio of 4.6 indicates the itinerant nature of ferromagnetism in Fe 5 AsTe 2 . |
