An unprecedented fully reduced {Mo V 60 } polyoxometalate: from an all-inorganic molecular light-absorber model to improved photoelectronic performance.
Autor: | Li XX; Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Department of Chemistry, Northeast Normal University Ren Min Street No. 5268 Changchun Jilin 130024 P. R. China chenwc061@nenu.edu.cn wangxl824@nenu.edu.cn., Ji T; Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Department of Chemistry, Northeast Normal University Ren Min Street No. 5268 Changchun Jilin 130024 P. R. China chenwc061@nenu.edu.cn wangxl824@nenu.edu.cn., Gao JY; Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Department of Chemistry, Northeast Normal University Ren Min Street No. 5268 Changchun Jilin 130024 P. R. China chenwc061@nenu.edu.cn wangxl824@nenu.edu.cn., Chen WC; Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Department of Chemistry, Northeast Normal University Ren Min Street No. 5268 Changchun Jilin 130024 P. R. China chenwc061@nenu.edu.cn wangxl824@nenu.edu.cn., Yuan Y; Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Department of Chemistry, Northeast Normal University Ren Min Street No. 5268 Changchun Jilin 130024 P. R. China chenwc061@nenu.edu.cn wangxl824@nenu.edu.cn., Sha HY; Department of Chemical Engineering, University of California Davis CA 95616 USA., Faller R; Department of Chemical Engineering, University of California Davis CA 95616 USA., Shan GG; Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Department of Chemistry, Northeast Normal University Ren Min Street No. 5268 Changchun Jilin 130024 P. R. China chenwc061@nenu.edu.cn wangxl824@nenu.edu.cn., Shao KZ; Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Department of Chemistry, Northeast Normal University Ren Min Street No. 5268 Changchun Jilin 130024 P. R. China chenwc061@nenu.edu.cn wangxl824@nenu.edu.cn., Wang XL; Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Department of Chemistry, Northeast Normal University Ren Min Street No. 5268 Changchun Jilin 130024 P. R. China chenwc061@nenu.edu.cn wangxl824@nenu.edu.cn., Su ZM; Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Department of Chemistry, Northeast Normal University Ren Min Street No. 5268 Changchun Jilin 130024 P. R. China chenwc061@nenu.edu.cn wangxl824@nenu.edu.cn. |
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Jazyk: | angličtina |
Zdroj: | Chemical science [Chem Sci] 2022 Mar 24; Vol. 13 (16), pp. 4573-4580. Date of Electronic Publication: 2022 Mar 24 (Print Publication: 2022). |
DOI: | 10.1039/d1sc06779f |
Abstrakt: | Fully reduced polyoxometalates are predicted to give rise to a broad and strong absorption spectrum, suitable energy levels, and unparalleled electronic and optical properties. However, they are not available to date. Here, an unprecedented fully reduced polyoxomolybdate cluster, namely Na Competing Interests: There are no conflicts to declare. (This journal is © The Royal Society of Chemistry.) |
Databáze: | MEDLINE |
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