| Autor: |
Neary WJ; Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306-4390, United States., Kennemur JG; Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306-4390, United States. |
| Jazyk: |
angličtina |
| Zdroj: |
ACS macro letters [ACS Macro Lett] 2019 Jan 15; Vol. 8 (1), pp. 46-56. Date of Electronic Publication: 2018 Dec 20. |
| DOI: |
10.1021/acsmacrolett.8b00885 |
| Abstrakt: |
This Viewpoint highlights the viability and increasing variety of functionalized polypentenamers as unique and valuable materials created through enthalpy-driven ring-opening metathesis polymerization (ROMP) of low ring strain cyclopentene monomers. The terms "low ring strain" and "enthalpy-driven" are typically conflicting ideologies for successful ROMP; however, these monomers possess a heightened sensitivity to reaction conditions, which may be leveraged in a number of ways to provide performance elastomers with good yield and precise functional topologies. Over the last several years, a rekindled interest in these systems has led to a renaissance of research aimed at improving their synthesis and exploring their potential. Their chemistry, applications, and future outlook are discussed. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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