Polymer Mechanochemistry: Force Enabled Transformations.
| Autor: | Wiggins KM; Department of Chemistry and Biochemistry, University of Texas at Austin, 1 University Station A1590, Austin, Texas 78712, United States., Brantley JN; Department of Chemistry and Biochemistry, University of Texas at Austin, 1 University Station A1590, Austin, Texas 78712, United States., Bielawski CW; Department of Chemistry and Biochemistry, University of Texas at Austin, 1 University Station A1590, Austin, Texas 78712, United States. |
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| Jazyk: | angličtina |
| Zdroj: | ACS macro letters [ACS Macro Lett] 2012 May 15; Vol. 1 (5), pp. 623-626. Date of Electronic Publication: 2012 Apr 20. |
| DOI: | 10.1021/mz300167y |
| Abstrakt: | In this viewpoint, we highlight the ability of mechanical force to overcome the limitations associated with using thermal or photochemical stimuli to facilitate chemical transformations. Emphasis will be directed toward examples of new chemical reactions that are accessed through externally applied mechanical forces, as these are illustrative of the emerging concept of using polymer chemistry to drive the synthesis of small molecules. In parallel, we offer perspectives on the potential applications of polymer mechanochemistry in the development of novel synthetic strategies. |
| Databáze: | MEDLINE |
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